Way back in 2004, Chemical Industry Vision 2020 - Ionic Liquids (ILs) (http://www.chemicalvision2020.org/ionic_liquids.html) convened a number of experts in the field to create a roadmap intended to eliminate the barriers to commercialization of ILs.
Desulfurization of hydrocarbon streams is one of the potential areas of IL application. Even though the Vision is ancient by today’s standards, it produce a list of references to the technical literature that will be useful to serious researchers. For example …
Reviews on IL and Catalysis
1.T. Weldon, Chem. Rev., 1999, 99, 2071-2083.
2.H. Olivier-Bourbigou, J. Mol. Catal. A: Chem.,1999, 146, 285-289.
3.P. Wasserscheidand W. Keim, Angew. Chem. Int. Ed., 2000, 39, 3772-3789.
4.R. Sheldon, Chem. Comm.,2001 (23), 2399-2407.
5.A. Ranwell, A. and M. A. Tshamano, ACS Symp. Ser., 818 (Ionic Liquids),2002, 147-160.
6.P. Wasserscheid, DGMK TagungsberichtProc. of the DGMK-Conference: Chances for Innovative Processes at the Interface between Refining and Petrochemistry, 2002, 97-106.
7.J. Dupont, R.F. de Souzeand P.A.Z. Suarez, Chem. Rev., 2002 102, 3667-3692.
8.H. Olivier-Bourbigouand L. Magna, J. Mol. Catal. A: Chem., 2002, 182/183, 419-437.
9.D. Zhao, M. Wu, Y. Kou and E. Min, Catal. Today, 2002, 74, 157-189.
10.V.P.W. Boehm, Applied Homogeneous Catalysis with Organometallic Compounds(2nd Edition,) 2002, 2, Wiley-VCH Verlag, 639-645.
11.P. Wasserscheid, Green Industrial Applications of Ionic Liquids, 2003, KluwerAcademic Pub., 29-47.
12.H. Olivier-Bourbigouand F. Huges, Green Industrial Applications of Ionic Liquids, 2003, KluwerAcademic Pub., 67-84.
13.A.J. Carmichael and D.M. Haddleton, Ionic Liquids in Synthesis, 2003, Wiley-VCH Verlag, 319-335.
14.H. Olivier-Bourbigouand A. Forestiere,Ionic Liquids in Synthesis, 2003, Wiley-VCH Verlag, 258-280.
source:
Catalysis and Ionic Liquids
Jeff Miller
(BP Chemicals)
Chemical Industry Vision 2020 Technology Partnership Workshop
“Barriers to Ionic Liquid Commercialization”
September 11, 2003
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Published ionic liquids roadmap: Accelerating Ionic Liquid Commercialization - Research Needs to Advance New Technology (PDF 1.8 MB).
The DOE Office of Basic Energy Sciences included fundamental research in ionic liquids in its SBIR solicitation and referred potential respondents to the Vision2020 Ionic Liquids Roadmap.
Published a thorough literature search on the industrial applications of ionic liquids and potential applications of ionic liquids. See the results of the literature search (PDF 226 KB). Technical Summaries on Ionic Liquids in Chemical Processing, Sheng Dai, David DePaoli, Mark Dietz, Jimmy Mays, Joanna McFarlane, William Steele. Oak Ridge National Laboratory, Argonne National Laboratory, University of Tennessee. 2003. (PDF 393 KB)
Ionic Liquids Reference Lists, Robin Rogers (PDF 565 KB)
"Barriers to Ionic Liquid Commercialization" Workshop Presentations
Catalysis and Ionic Liquids, Jeff Miller, BP Chemicals. (PDF 1.8 MB)
Overview: Technical Summaries on Ionic Liquids in Chemical Processing, David DePaoli, Oak Ridge National Laboratory. (PDF 220 KB)
Overview: Industrial Application of Ionic Liquids for Liquid Extraction, Jeff Kanel, J.S. Kanel & Associates. (PDF 191 KB)
"Barriers to Ionic Liquid Commercialization" Workshop Results, BCS, Incorporated. (PDF 172 KB)
source: http://www.chemicalvision2020.org/ionic_liquids.html
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Reference Lists for Ionic Liquids
Provided by: Professor Robin D. Rogers Department of Chemistry The University of Alabama Tuscaloosa, AL 35487 Telephone (205) 348-4323 FAX (205) 348-0823 E-Mail: rdrogers@bama.ua.edu
Ionic Liquids and Separations 2-5-04
Reference List page 2
Ionic Liquids and Chemical Processes 2-8-04
Reference List page 15
Ionic Liquids in Polymerization Reactions 1-22-04
Reference List with Abstracts page 16
Ionic Liquids Fuel Applications 2-5-044
Reference List page 78
source: http://www.chemicalvision2020.org/ionic_liquids.html
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References
Abuadoun, I.I. 1989. “Photoinitiated cationic polymerization by imidazolium salts”, Abst. Papers Am. Chem. Soc. 198, 96.
Adams, C.J., Earle, M.J., Roberts, G. and Seddon, K.R. 1998. “Friedel-Crafts reactions in room temperature ionic liquids”, Chem. Commun, 2097-2098.
Afonso, C.A.M. 2002, Angew. Chem. Int. Ed 41, 2771.
Aida, T. and Fukushima, T. 2003. Science 300, 2072.
Anthony, J.L., Brennecke, J.F., Holbrey, J.D., Maginn, E.J., Mantz, R.A., Rogers, R.D., Trulove, P.C., Visser, A.E. and Welton, T. “Physicochemical properties of ionic liquids: melting points and phase diagrams”, in Ionic Liquids in Synthesis, P. Wasserscheid and T. Welton (Eds.), Wiley-VCH Verlag GmbH&Co. KGaA, Weinhein, Germany, 41-55.
Anthony J.L., Maginn, E.J., Brennecke, J.F. “Solution thermodynamics of imidazolium-based ionic liquids and water,” J. Phys. Chem. B 105, 10942-10949 (2001).
Anthony J.L., Maginn, E.J., Brennecke, J.F. “, J. Phys. Chem. B 105, 10942-10949 (2001).
Armstrong, D.W., He, L. and Liu, Y. 1999. “Examination of ionic liquids and their interaction with molecules, when used as stationary phases in gas chromatography”, Anal. Chem., 71, 3873.
Atkins, M.P., Bowlas, C., Ellis, B., Hubert, F., Rubatto, A., Wasserscheid, P. 2003. “Ionic liquids as catalysts for ethylbenzene production”, in Green Industrical Applications of Ionic Liquids, NATO Science Series II: Mathematics, Physics and Chemistry 92, Kluwer Academic Publishers, Dordrecht, 49-66.
Ball, P. 2001. “Fuels Clean Up”, Nature, Dec. 31.
Bartsch, R.A., Chun, S. and Dzyuba, S.V. 2002. “Ionic liquids as novel diluents for solvent extraction of metal salts by crown ethers”, ACS Symposium Series 818, 58-68.
Baston, G.M.N., Bradley, A.E., Gorman, T., Hamblett, I., Hardacre, C., Hatter, J.E., Healy, M.J.F., Hodgson, B., Lewin, R., Lovell, K.V., Newton, G.W.A., Nieuwenhuyzen, M., Pitner, W.R., Rooney, D.W., Sanders, D., Seddon, K.R., Simms, H.E., Theid, R.C. 2002. “Ionic liquids for the nuclear industry: A radiochemical, structural and electrochemical investigation”, ACS Symposium Series 818, 162-177.
Bates, E.D., Mayton, R.D., Ntai, I. and Davis, J.H. 2002. “CO2 capture by a task-specific ionic liquid”, J. Am. Chem. Soc., 124, 926.
Bent, M., Wasserscheid, P. and Gmehling, J. “Meausurement of activity coefficients at infinite dilution in ionic liquids using the dilutor technique”, submitted to the J. Chemical and Engineering Data.
Benton, M. G., and C.S. Brazel, “Comparison of Kinetics For Solution Polymerization of Poly(methyl methacrylate) in Green Ionic Liquid Solvents Versus Traditional Volatile Solvents,” Polym. Prepr., 2002, 43, 881.
Biedron, T., and P. Kubisa, “ATRP of Acrylates in an Ionic Liquid”, Macromol. Rapid Commun., 2001, 22, 1237.
Biedron, T., and P. Kubisa, “ATRP of Acrylates in an Ionic Liquid: Synthesis of Block Copolymers”, J. Polym. Sci., Part A-Polym. Chem., 2002, 40, 2799.
Blanchard, L.A.; Brennecke, J.F. “Recovery of organic products from ionic liquids using supercritical carbon dioxide,” Ind. Eng. Chem. Res. 40, 287 (2001).
Blanchard, L.A.; Gu, Z.; Brennecke, J.F. “High-pressure phase behavior of ionic liquid/CO2 systems,” J. Phys. Chem. B 105, 2437 (2001).
15
Blanchard, L.A., Hancu, D., Beckman, E.J., Brennecke, J.F. “Green processing using ionic liquids and CO2,” Nature 399, 28-29 (1999).
Boesmann, A., Datsevich, L., Jess, A., Lauter, A. Schmitz, C. and Wassercheid, P. 2001. “Deep desulfurization of diesel fuel by extraction with ionic liquids”, Chemical Communications, 23, 2494-2495.
Boesmann, A., Francio, G., Janssen, E., Solinas, M., Leitner, W. and Wasserscheid, P. “Activation, tuning, and immobilization of homogeneous catalysts in a ionic liquid/compressed CO2 continuous-flow system,” Angew. Chem. Int. Ed. 40, 2697-2698 (2001).
Boon, J.A., Levisky, J.A., Pflug, J.L. and Wilkes, J.S. 1986. “Friedel Crafts reactions in ambient-temperature molten-salts”, J. Organic Chemistry 51, 480-483.
Branco, L.C.; Crespo, J.G.; Afonso, C.A.M. “Highly selective transport of organic compounds by using supported liquid membranes based on ionic liquids,” Angew. Chem. Int. Ed. 41, 2771 (2002).
Branco, L.C.; Crespo, J.G.; Afonso, C.A.M. Chem. Eur. J. 8, 3865 (2002).
Brasse, C.C., Englert, A., Salzer, A., Waffenschmidt, H. and Wasserscheid, P. 2000. “Ionic phosphine ligands with cobaltocenium backbone -Novel ligands for highly selective, biphasic Rh-catalysed hydroformylation of 1-octene using ionic liquids”, Organometallics, 19, 3818-3823.
Brauer, D.J., Kottsieper, K.W., Lief, C., Stelzer, O., Waffenschmidt, H. and Wasserscheid, P. 2001. “Phosphines with 2-imidazolium and para-phenyl-2-imidazolium moieties – Synthesis and application in two phase catalysis”, J. Organometallic Chemistry 630(2).
Brennecke, J.F. and Maginn, E.J. 2003. Purification of gas with liquid ionic compounds, US patent 6,579,343.
Brennecke, J.F. and Maginn, E.J. 2001. “Ionic Liquids: Innovative fluids for chemical processing,” AIChE J. 47, 2384.
Brennecke, J.F. 2002, J. Am. Chem. Soc., 124, 10276.
Bugle, R.C., Wilson, K. Olsen, G., Wade, L.G. Jr., Osteryoung, R.A. 1978. Nature, 274, 578-580.
Butler, R. 2001. “Ionic solution to chemistry problems”, Chemistry and Industry 17, 532.
Carlin, R. T., and J.S. Wilkes, "Complexation of Cp2MCl2 in a Chloroaluminate
Molten Salt: Relevance to Homogeneous Ziegler-Natta Catalysis", J. Molec. Catalysis, 1990, 125. Carmichael, A. J., D.M. Haddleton, S.A.F. Bon, and K.R. Seddon, "Copper(1) Mediated Living Radical Polymerisation in an Ionic Liquid," Chem Commun., 2000, 1237.
Carmichael, A.J. and Haddleton, D.M. 2003. “Polymer synthesis in ionic liquids”, in Ionic Liquids in Synthesis, P. Wasserscheid and T. Welton (Eds.), Wiley-VCH Verlag GmbH&Co. KGaA, Weinhein, Germany, 319-335.
Carper, W.R., Doelle, A. and Meng, A. 2002. “Gas phase models of ionic liquids: Semi-empirical and ab initio bonding and molecular structure”, presented at 223rd ACS National Meeting, Orlando, FL, April 7-11, 2002.
Chauvin, Y. and Olivier-Bourbigou, H. 1995. “Nonaqueous ionic liquids and reaction solvents,” Chemtech 25, 26-30.
Chauvin, Y., Einloft, S. and Olivier, H. 1995. “Catalytic dimerization of propoene by nickelphosphine
complexes in 1-butyl-3-methylimidazolium chloride/AlEtxCl3-x (x=0,1) ionic liquids.” Ind. Eng. Chem. Res. 34, 1149-1155.
16
Chauvin, Y., Mussman, L. and Olivier, H. 1996. "A Novel Class of Versatile Solvents for 2-Phase Catalysis - Hydrogenation, Isomerizaiton, and Hydroformylation of Alkenes Catalyzed by Rhodium Complexes in Liquid 1,3- Dialkylimidazolium Salts," Angew. Chem.-Internat. Ed. Eng. 34, 2698.
Cole, A.C, Jensen, J.L. , Ntai, I., Tran, K.L.T., Weaver, K.J., Forbes, D.C., and Davis Jr., J.H. 2002. J. Am. Chem. Soc., 124, 5862.
Cornerstone, M., Wasserscheid, P. and Kragl, U. “Influence of water activity and temperature on enzymatic kinetics”, submitted to Biotechnical Letters.
Cornils, B. and Herrmann, W.A. 2003. Concepts in homogeneous catalysis: the industrial view, Journal of Catalysis 216, 23-31.
Csihony, S., C. Fischmeister, C. Bruneau, I. T. Horvath, and P. Dixneuf, “First Ring Opening Metathesis Polymerization in an Ionic Liquid”, New Journal of Chemistry, 2002, 26, 1667.
Dai S., Ju Y.H. and Barnes, C.E. 1999. “Solvent extraction of strontium nitrate by a crown ether using room-temperature ionic liquids”, J. Chem. Soc., Dalton Trans. 8, 1201-1202.
Davis, J.H. 2003. “Synthesis of task-specific ionic liquids”, in Ionic Liquids in Synthesis, P. Wasserscheid and T. Welton (Eds.), Wiley-VCH Verlag GmbH&Co. KGaA, Weinhein, Germany, 28-40.
Davis Jr., J.H., Mayton, R., Jensen, J., Ntai, I. 2002. “Task specific ionic liquids of potential petroleum and petrochemical utility”, presented at 223rd ACS National Meeting, Orlando, FL, April 7-11, 2002.
Davis, J.H., and Fox, P.A. 2003. “From curiosities to commodities: ionic liquids begin the transition”, Chemical Communications, 1209-1212.
Davis, J.H., Gordon, C.M, Hilgers, C. and Wasserscheid, P. “Synthesis and purification of ionic liquids”, in Ionic Liquids in Synthesis, P. Wasserscheid and T. Welton (Eds.), Wiley-VCH Verlag GmbH&Co. KGaA, Weinhein, Germany, 7-21.
Diedenhofen, M., Eckert, F., and Klamt, A. 2003. “Prediction of infinite dilution activity coefficients of organic compounds in ionic liquids using COSMO-RS,” J. Chem. Eng. Data 48, 475-479.
Dietz, M.L.; Dzielawa, J.A. Chem. Comm. 2124 (2001).
Driessen-Hoel, B., Wasserscheid, P. and Keim, W. 1998. “Recycle of homogeneous transition metal catalysts in two liquid phases”, Cattech, 3, 47-52.
Dupont, J., de Souza, R.F. and P.A. Z. Suarez. 2002. “Ionic liquid (molten salt) phase organometallic catalysis”, Chem. Rev. 102, 3667.
Dutta, L.M. 1994. “The dissolution of Liassic kerogen and coal”, Thesis of M.Phil, U. of Sussex.
Earle, M.J. 2002. “Ionic liquids: Solvents for the twenty-first century”, ACS Symposium Series 818, 90-105.
Eike, D.M.; Brennecke, J.F.; Maginn, E.J. Green Chem. 5, 323 (2003).
Ellis, B., Keim, W., Wasserscheid, P. 1999. “Linear dimerisation of 1-butene in biphasic mode using buffered chloroaluminate ionic liquid solvents”, Chemical Communications, 337-338.
Erbeldinger, M., Mesiano, A.J. and Russell, A.J. 2000. “Enzymatic catalysis of formation of Z-aspartame in ionic liquid-an alternative to enzymatic catalysis in organic solvents”, Biotechnol. Prog., 16, 1129.
Fehrmann, R., Ericksen, K.M., Rasmussen, S.B., Winnik, J. 2003. “Ionic liquids as catalysts for sulfuric acid production and cleaning of flue gases”, in Green Industrical Applications of Ionic
17
Liquids, NATO Science Series II: Mathematics, Physics and Chemistry 92, Kluwer Academic Publishers, Dordrecht, 253-262.
Fraga-Dubreuil, J. and Bazureau, J.P. 2001. Tetrahedron Letters 42, 6097.
Fraga-Dubreuil, J. and Bazureau, J.P. 2001. Tetrahedron Letters 41, 7352.
Fraga-Dubreuil, J. and Bourahla, K., Rahmouni, M., Bazureau, J.P. and Hamelin, J. 2002. Catalysis Communications 3, 185.
Freemantle, M. 2000. “Eyes on Ionic Liquids”, Chemical and Engineering News, 78(20), 37-50.
Freemantle, M. 2002. “Ionic liquid yields network”, Chemical and Engineering News, December 2, 2002.
Freemantle, M. 2002. “New gel for solar cell”, Chemical and Engineering News, December 23, 2002.
Freemantle, M. 2003a. “BASF’s smart ionic liquid”, Chemical and Engineering News, March 31, 2003, p.9.
Freemantle, M. 2003. “Ionic liquids go bucky”, Chemical and Engineering News, June 30, 2003.
Germ, W., Vogt, M., Wasserscheid, P., Driessen-Hoel, B. 1999. “Perfluorination of polyethers for the immobilisation of homogeneous nickel catalyst”, J. Mol. Cat, 171-175.
Germ, W. Vogt, D., Waffenschmidt, H., and Wasserscheid, P. 1999. “New method to recycle homogeneous catalysts from monophasic reaction mixtures by using ionic liquid exemplified for the Rh-catalysed hydroformylation of methyl-3-pentenoate”, J. Catalysis, 186, 481-484.
Goldenberg, L. M., and R.A. Osteryoung, "Benzene Polymerization in 1-ethyl-3-methylimidazolium chloride-AlCl3 Ionic liquid," Synth. Metals, 1994, 64 63.
Gordon C. M. 2001. “New developments in catalysis using ionic liquids,” Applied Catalysis A-General 222 (1-2), 101-117.
Hall, H.P. 2001. “Those baffling ionic liquids”, Chemistry and Industry 9, 262.
Hanke, C.G., Johansson, A., Harper, J.B. and Lynden-Bell, R.M. 2003. “Why are aromatic compounds more soluble than aliphatic compounds in dimethylimidazolium ionic liquids? A simulation study”, Chemical Physics Letters, 374(1,2), 85-90.
Hardacre, C., J. D. Holbrey, S. P. Katdare, and K. R. Seddon, “Alternating Copolymerization of Styrene and Carbon Monoxide in Ionic Liquids”, Green Chemistry, 2002, 4, 143.
Harrisson, S., S. Mackenzie, and D.M. Haddleton, "Pulsed Laser Polymerization of Methyl Methacrylate in Ionic Liquids," Polym. Prepr., 2002, 43 883; Chem. Commun., 2002, 2850.
Harrisson, S., S. R. Mackenzie, and D. M. Haddleton, “Pulsed Laser Polymerization in an Ionic Liquid: Strong Solvent Effects on Propagation and Termination of Methyl Methacrylate”, Macromolecules, 2003, 36, 5072.
Holbrey, J.D. and Seddon, K.R. 1999. “Ionic liquids”, Clean Products and Processes, 1, 223-236.
Holbrey, J.D. and Rogers, R.D. 2002. in Ionic Liquids: Industrial Applications in Green Chemistry, R.D. Rogers and K.R. Seddon (Eds.), ACS Symposium Series 818, American Chemical Society, Washington DC, 2.
Hong, K., H. Zhang, J.W. Mays, A.E. Visser, C.S. Brazel, J.D. Holbrey, W.M. Reichert, and R.D. Rogers, "Conventional Free Radical Polymerization in Room Temperature Ionic Liquids: A Green Approach to Commodity Polymers with Practical Advantages," Chem. Commun., 2002, 1368.
Huang, B.-C. and Huang, Z.-T. 2003. “Research in ionic liquids and their application in catalysis”, Gongye Cuihua 11(2), 1-6.
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Huddleston, J.G., Visser, A.E., Reichert, W.M., Willauer, H.D., Kroker, G.A. and Rogers, R.D. 2001. “Characterization and comparison of hydrophilic and hydrophobic room temperature ionic liquids incorporating the imidazolium cation”, Green Chemistry 3, 156.
Huddleston, J.G.; Willauer, H.D.; Swatloski, R.P.; Visser, A.E.; Rogers, R.D. Chem. Commun., 1765 (1998).
Jastorff, B., Stormann, R., Ranke, J., Molter, K., Stock, F., Oberheitmann, B., Hoffmann, J, Nuchter, M., Ondruschka, B., and Filser, J. 2003 “How hazardous are ionic liquids? Structure-activity relationships and biological testing as important elements for sustainability evaluation,” Green Chemistry 5, 136-142.
Jensen, M.P.; Dzielawa, J.A.; Rickert, P.; Dietz, M.L. J. Am. Chem. Soc. 124, 10664 (2002).
Jess, A., Leuchtenberger, W., Reschetilowski, W., Wasserscheid, P. 2000. “Trend report in technical chemistry 1999”, Messages From Chemistry, 48, 359-363.
Jiang, T.-F.; Gu, Y.-L.; Liang, B.; Li, J.-B.; Shi, Y.-P.; Ou, Q.-Y. Anal. Chim. Acta 479, 249 (2003).
Johnson, KE, Xiao L, Driver G. 2002. “Significance of cations in ionic liquids chemistry,” in Ionic Liquids: Industrial Applications in Green Chemistry, R.D. Rogers and K.R. Seddon (Eds.), ACS Symposium Series 818, American Chemical Society, Washington DC, 230-240.
Katritsky, A.R.; Lomaka, A.; Petrukhin, R.; Jain, R.; Karelson, M.; Visser, A.E.; Rogers, R.D. J. Chem. Inf. Comput. Sci. 42, 71 (2002).
Kaufmann, D.E., Nouroozian, M. and Henze, H. 1996. “Molten salts as an efficient medium for palladium-catalysed C-C coupling reactions”, Synlett, 1091
Koel, M., Ljovin, S., Hollis, K., Rubin, J. 2001. “Using neoteric solvents in oil shale studies”, Pure and Applied Chemistry, 73, 153-159.
Koel, M., Hollis, K., Rubin, J., Lombardo, T. and Smith, B. 2003. “Ionic liquids for oil shale treatment”, in Green Industrical Applications of Ionic Liquids, NATO Science Series II: Mathematics, Physics and Chemistry 92, Kluwer Academic Publishers, Dordrecht, 193-207.
Koen, R.D., Haufe, M., Kociok-Koehn, G., Grimm, S., Wasserscheid, Keim, W. 2000. “A new conversion for �-olefin: Selective trimerization with triazacyclohexane complexes of the chrome as catalysts”, Angew. Chem. 112, 4519-4522.
Klamt., A. and Eckert, F. 2000. “COSMO-RS: A novel and efficient method for the a priori prediction of the thermophysical data of liquids”, Fluid Phase Equilibria, 172, 43.
Kobryanskii, V. M., and S.A. Arnautov, "Chemical Synthesis of Polyphenylene in an Ionic Liquid," Synth. Metals, 1993, 55, 924.
Kosmulski, M., Marczewska-Boczkowska, K., Saneluta, C. 2002. “Low temperature ionic liquids - a laboratory curiosity or a technological revolution. Part 2. Applications of ionic liquids in organic synthesis and in extraction”, Przemysl Chemiczny 81 (2), 106-110.
Kragl, U., Kaftzik, N., Schoefer, S.H., Eckstein, M., Wasserscheid, P. and Hilgers, C. 2001. “Enzymatic catalysis in the presence of ionic liquids”, Chemistry Today, 19(7/8), 22-24.
Kragl, U., Eckstein, M. and Kaftzik, N. 2003. “Biocatalytic reactions in ionic liquids”, in Ionic Liquids in Synthesis, P. Wasserscheid and T. Welton (Eds.), Wiley-VCH Verlag GmbH&Co. KGaA, Weinhein, Germany, 336-347.
Kottsieper, K.W., Stelzer, and Wasserscheid, P. 2001. “1-vinylimidazole – A versatile building block for the synthesis of cationic phosphines useful in ionic liquids biphasic catalysis”, J. Mol. Catal. 175, 285-288.
Li, J., Wherland, S. 2002. Chemical Communications, 2872.
19
Ma, Y.H., X. H. Wan, X. F. Chen, and Q. F. Zhou, “Reverse ATRP of MMA in Room Temperature Ionic Liquid”, J. Polym. Sci., Part A-Polym. Chem., 2003, 41, 143.
Mantz, R.A. and Trulove, P.C. 2003. “Viscosity and density of ionic liquids”, in Ionic Liquids in Synthesis, P. Wasserscheid and T. Welton (Eds.), Wiley-VCH Verlag GmbH&Co. KGaA, Weinhein, Germany, 56-68.
Margulis, C. J., Stern, H. A., and Berne, B. J. 2002. “Computer simulation of a ‘green chemistry’ room-temperature ionic solvent,” J. Phys. Chem. B 106, 12017-12021.
Marsh, K., Deev, A. A.C-T. Wu, Tran, E. and Klamt A. 2002. “Room temperature ionic liquids as replacements for conventional solvents – A review”, Korean J. Chem. Eng., 19, 357-362.
Mathews, C.J., Smith, P.J., Welton, T. White, A.J.P. and Williams, D.J. 2001. “In situe formation of mixed phosphine-imidazolyidene palladium complexes in room-temperature ionic liquids”, Organometallics 20(18), 3848-3850.
Medved, M., Wasserscheid, P., and Melin, T. 2001. “Potential use of ionic liquids in diaphragm technology applications”, Proceedings of the 8th Aachener Diaphragm Colloquium, 123-127.
Medved, M., Wasserscheid, P., and Melin, T. 2001. “Ionic liquids as active separation layer in supported liquid membranes”, Chemical Engeering Technology, 73, 715.
Mehnert, C.P., Cook, R.A., Dispenzire, N.C. and Afeworki, M. 2003. Supported ionic liquid catalysis – A new concept for homogeneous hydroformulation catalysis, J. Am. Chem. Soc. 124, 12932-12933.
Moens, L. and Khan, N. 2000. “Chemistry with carboyhydrates and lignins in room temperature ionic liquids”, Abstr. Pap. Am. Chem. Soc 219, 87-IEC Part 1.
Morrow, T. I., and Maginn, E. J. 2002. “Molecular dynamics study of the ionic liquid 1-n-butyl-3-methylimidazolium hexafluorophosphate,” J. Phys. Chem. B 106, 12807-12813.
Muathen, H.A. 1992. J. Org. Chem. 57, 2740.
Najdanovic-Visak, V., Esperanca, J.M.S.S., Rebelo, L.P.N., da Ponte, M,N,, Guedes, H.J.R., Seddon, K.R., Szydlowski, J. 2002. “Phase behaviour of room temperature ionic liquid solutions: an unusually large co-solvent effect in (water plus ethanol)”, Physical Chemistry Chemical Physics 4(10), 1701-1703.
Nelson, W.M. 2002. “Are ionic liquids green solvents?”, ACS Symposium Series 818, 30-41.
Noda, A., and M. Watanabe, “Highly conductive polymer electrolytes prepared by in situ polymerization of vinyl monomers in room temperature molten salts,” Electrochim. Acta, 2000, 45, 1265.
Nunes, V.M.B, Lourenco, M.J.V., Santos, F.J.V., Neitro de Castro, C. A., “Importance of accurate data on viscosity and thermal conductivity in molten salts applications,” J. Chem. Eng. Data 48 446-450 (2003).
Oldham Jr., W.J., Costa, D.A. and Smith, W.H. 2003. “Development of room-temperature ionic liquids for applications in actinide chemistry”, ACS Symposium Series 818, 188-198.
Olivier. 1999. “Recent developments in the use of non-aqueous ionic liquids in two-phase catalysis”, J. Molec. Catal. A, 146, 285-289.
Olivier-Bourbigou, H. and Magna, L. 2002. “Ionic liquids: Perspectives for organic and catalytic reactions”, J. Molec. Catal. A. 182-183, 419-437.
Ohno, H. 2003. “Ionic liquid: The front and future of material development”. In Ionsei Ekitai, Shi Emu Shuppan Co, Ltd., Tokyo, Japan
Ohno, H. 2003. “Importance and prospects of ionic liquids”. In Ionsei Ekitai, Shi Emu Shuppan Co, Ltd., Tokyo, Japan, Mirai Zairyo 2(9), 6-11.
20
Ota. E. 1987. Some aromatic reactions using AlCl3-rich molten salts. J. Electrochem. Soc 134, C512.
Owens, G.S. 2001. “Methyltrioxorhenium-catalyzed oxygen transfer reactions in ambient temperature ionic liquids”, Thesis University of California, Los Angeles, CA, USA.
Pagni, R.M. 2003. “Ionic liquids as alternatives to traditional organic and inorganic solvents”, in Green Industrial Applications of Ionic Liquids, NATO Science Series II: Mathematics, Physics and Chemistry, 92, Kluwer Academic Publishers, Dordrecht, 105-127.
Patell. 1993. “The dissolution of kerogens”, Thesis of M.Phil, U. of Sussex.
Perrier, S., T. P. Davis, A. J. Carmichael, and D. M. Haddleton, Eur. Polym. J., 2003, 39, 417. Perry, R.L., Jones, K.J., Scott, W.D., Qing Liao, Hussey, C.L. 1995. J. Chem. Eng. Data, 40, 615-619.
Pitner, W.R., Bradley, A.E., Rooney, D.W., Sanders, D., Seddon, K.R., Thied, R.C. and Hatter, J.E. 2003. “Ionic liquids in the nuclear industry: Solutions for the nuclear fuel cycle”, in Green Industrial Applications of Ionic Liquids, NATO Science Series II: Mathematics, Physics and Chemistry, 92, Kluwer Academic Publishers, Dordrecht, 209-226.
Ranwell, A. and Tshamano, M.A. 2002. “Potential application of ionic liquids for olefin oligomerization”, ACS Symposium Series 818, 147-160.
Ridenour, W.B. and McFarlane, J. 2003. The removal of organic contaminants from produced water with ionic liquids. To be presented at the 13th Separation Science and Technology Symposium, Gatlinburg, TN, October 2003.
Rogers, R. and Seddon, K. (Eds.) 2002. Ionic Liquids: Industrial Applications to Green Chemistry, ACS Symposium Series 181, American Chemical Society, Washington, DC.
Rogers, R., Seddon, K. and Volkov, S. (Eds.) 2003. Green Industrial Applications of Ionic Liquids, NATO Science Series II: Mathematics, Physics and Chemistry, 92, Kluwer Academic Publishers, Dordrecht.
Ryan, D.M. 2000. “Electrochemistry and spectroscopy of electrolytes and cathode materials in room-temperature ionic liquids”, Thesis Miami University, Oxford, OH, USA.
Sarbu, T., and K. Matyjaszewski, "ATRP of Methyl Methacrylate in the Presence of Ionic Liquids with Ferrous and Cuprous Anions," Macromol. Chem. Phys., 2001, 202, 3379.
Schäfer, T.; Rodrigues, C.M.; Afonso, C.A.M.; Crespo, J.G. “Selective recovery of solutes from ionic liquids by pervaporation – a novel approach for purification and green processing,” Chem. Comm. 1622 (2001).
Schoefer, S.H., Kaftzik, N., Wasserscheid, P. and Kragl, U. 2001. “Enzymatic catalysis in ionic liquids II: Lipase catalysed kinetic resolution of 1-phenylethanol with improved enantioselectivity”, Chemical Communication, 425-426.
Scurto, A.M.; Aki, S.N.V.K.; Brennecke, J.F. “CO2 as a separation switch for ionic liquid/organic mixtures,” J. Am. Chem. Soc. 124, 10276 (2002).
Scurto, A.M.; Aki, S.N.V.K.; Brennecke, J.F. “Carbon dioxide induced separation of ionic liquids and water,” Chem. Comm. 572 (2003)
Seddon, K. 2003. “Ionic liquids: A taste of the future”, Nature Materials, 2(60), 363-365.
Sheldon, R. 2001. “Catalytic Reactions in Ionic Liquids”, Chemical Communication. 2399-2407.
Skelton, A., White, H. and Englert, A. 2002. “Ni(II) heterocyclic carbene complexes as catalysts for olefin dimersation in imidazolium chloroaluminate ionic liquid”, Organometallics 21-175-181.
21
Snedden, P., A. I. Cooper, K. Scott, and N. Winterton, “Crosslinked Polymer-Ionic Liquid Composite Materials”, Macromolecules, 2003, 36, 4549.
Stenzel, O., R. Brull, U. M. Wahmer, R. D. Sanderson, and H. G. Raubenheimer, “Oligomerization of Olefins in a Chloroaluminate Ionic Liquid”, J. Mol. Catalysis A-Chemical, 2003, 192, 217.
Stone, S., Wasserscheid, P, Driessen Driessen-Hoel, B. 2000. “Ionic liquid as catalyst on medium for stereoselective hydrogenations of sorbic acid with ruthenium of complexes”, J. Prakt. Chem. 342, 348-354.
Suarez, P.A.Z., Dullius, J.E.L., Einoft, S., de Souza, R.F. and Dupont, J. 1997. “Two-phase catalytic hydrogenation of olefins by Ru(II) and Co(II) complexes dissolved in 1-n-butyl-3-methylimidazolium cation”, Inorganica Chimica Acta 255, 207.
Sung, D. 2000. “The chemistry of centered hexanuclear zirconium chloride clusters in ionic liquids and other nonaqueous solvents”, Thesis Texas A and M University.
Sutton, P.A., Lewis, C.A. and Rowland, S.J. 1998. “Attempted dissolution of 'insoluble organic matter' from Methanococcus jannaschii and Rostherne Mere (UK) sediment with 1-ethyl-3-methylimidazolium chloride/aluminium (III) chloride.” Ancient Biomolecules 2, 195-207.
Swatloski, R.P.; Holbrey, J.D.; Rogers, R.D. Green Chem. 5, 361 (2003).
Tang, J., and R. A. Osteryoung, “Formation and electrochemistry of polyaniline in ambient-temperature molten salts,” Synth. Metals, 1991, 45, 1.
Turner, E. A., Pye, C. C., and Singer, R. D. 2003. “Use of ab initio calculations toward the rational design of room temperature ionic liquids,” J. Phys. Chem. A 107, 2277-2288.
Visser, A.E., Swatloski, R.P., Reichert, W.M., Griffin, S.T. and Rogers, R.D. 2000. Traditional extractants in nontraditional solvents: Groups 1 and 2 extraction by crown ethers in room-temperature ionic liquids, Ind. Eng. Chem. Res. 39 (10), 3596-3604.
Visser, A.E.; Swatloski, R.P.; Reichert, W.M.; Mayton, R.; Sheff, S.; Wierzbicki, A.; Davis, J.H., Jr.; Rogers, R.D. “Task-specific ionic liquids for the extraction of metal ions from aqueous solutions,” Chem. Comm. 135 (2001).
Visser, A. E.; Swatloski, R. P.; Griffin, S. T.; Hartman, D. H.; Rogers, R. D. Sep. Sci. Technol. 36, 785 (2001).
Visser, A. E.; Swatloski, R. P.; Hartman, D. H.; Huddleston, J. G.; Rogers, R. D. In Calixarenes for Separations; Lumetta, G. J., Rogers, R. D., Gopalan, A S., Eds.; ACS Symposium Series 757; American Chemical Society, Washington, DC, 2000, pp. 223-236.
Visser, A.E.; Swatloski, R.P.; Reichert, W.M.; Mayton, R.; Sheff, S.; Wierzbicki, A.; Davis, J.H., Jr.; Rogers, R.D. “Task-specific ionic liquids incorporating novel cations for the coordination and extraction fo Hg2+ and Cd2+: Synthesis, characterization, and extraction studies,” Environ. Sci. Technol. 36, 2523 (2001).
Visser, A. E.; Swatloski, R. P.; Rogers R. D. “pH-dependent partitioning in room temperature ionic liquids,” Green Chemistry 2, 1 (2000).
Wasserscheid, P. 2003. “Potential to apply ionic liquids in industry: Exemplified for the use as solvents in industrial applications as homogeneous catalysis”, in Green Industrical Applications of Ionic Liquids, NATO Science Series II: Mathematics, Physics and Chemistry 92, Kluwer Academic Publishers, Dordrecht, 29-47.
Wasserscheid, P. 2001. “Ionic liquids – Innovative Solvents”, Messages from Chemistry, 49, 12-16.
22
Wassersheid, P. 2002. “Application of cationic nickel(II) complexes with biphosphine monoxide ligands into ethylene oligomerisation”, in Synthetic Methods of Organometallic and Inorganic Chemistry, W.A. Hermann (Ed.), 10, 180-184, Thieme, Stuttgart.
Wasserscheid, P. 1998. “The use of ionic liquids - By the example of the dimerization of 1-butene”, Thesis, RWTH Aachen.
Wasserscheid, P. 2002. “Biphasic hydroformylation of 1-octene using ionic liquids as catalysts”, in Green Industrial Applications of Ionic Liquids, (R. Rogers, Ed) ACS books.
Wasserscheid, P. and Eichmann, M. 2001. “Selective dimerisation in biphasic mode using buffered chloroaluminateionic liquid solvents. Design and application of a continuous loop reactor”, Catalysis Today, 66, 309-316.
Wasserscheid, P. and Keim, W. 2000. “Ionic liquids-New solutions for transition metal catalysis”, Agnew. Chem. Int. Ed., 39(21), 3772.
Wasserscheid, P. and Waffenschmidt, H. 2000. “Ionic liquids into regioselective, platinumcatalysed
hydroformylation”, J. Mol. Cat. A. 164, 61-67.
Wasserscheid, P., Jess, A. and Eichmann, M. 2000. “Two-phase dimerization from propene in ionic liquids”, Chem. Eng. Tech 72, 991-992.
Wasserscheid, P., Boesmann, A. and Bolm, C. 2002. “Synthesis and properties of ionic liquids derived from the chiral pool”, Chemical Communications, 200-201.
Wasserscheid, P., Hilgers, C. and Keim, W. 2002. “Ionic Liquids – weakly coordinating solvents for the biphasic ethylene oligomerization of olefins using cationic Ni-complexes”, in Green Industrial Applications of Ionic Liquids, (R. Rogers, Ed) ACS books.
Wasserscheid, P., Sesing, M. and Korth, W. 2002. “Hydrogensulfate and tetrakis(hydrogensulfato)borate ionic liquids – Synthesis and catalytic application in highly Bronsted acidic system for Freidel-Crafts alkylation”, Green Chemistry, in press.
Wasserscheid, P., Gordon, C.M., Hilgers, C., Muldoon, M.J., and Dunkin, I.R. 2001. “Ionic liquids – Polar, but weakly coordinating solvents for the roofridge biphasic oligomerisation of ethene”, Chemical Communications, 1186-1187.
Wasserscheid, P., Waffenschmidt, H., Machnitzki, P., Kottsieper, K.W., and Stelzer, O. 2001. “Cationic phosphine ligands with guanidiniumphenyl modified xanthene moieties. A successful concept for highly regioselective, biphasic hydroformylation of oct-1-ene in hexafluorophosphate ionic liquids”, Chemical Communciations, 451-452.
Wassersheid, P., Grimm, S., Koehn, R., M. Haufe. 2001. “Synthesis of synthetic lubricants by homogeneous Cr-catalyzed trimerisation of 1-decane and 1-dodecane”, Automatic Data Processing Synthetic Catalysis 343, 814-818.
Wasserscheid P., and Keim W. 2000. “Ionic liquids - New "solutions" for transition metal catalysis,” Angewandte Chemie-International Edition 39 (21), 3773-3789.
Welton. T. 1999. “Room Temperature Ionic Liquids. Solvents for Synthesis and Catalysis”, Chemical Review, 99, 2071-2083.
Welton, T. and Wasserscheid, P.(Eds.) 2002. Ionic Liquids in Synthesis, Wiley-VCH, Weinheim.
Wilkes, J.S. 2002. “Ionic liquids in perspective: The past with an eye toward the industrial future”, ACS Symposium Series 818, 214-229.
Wilkes, J. S., Zaworotko, M. J. J. Chem. Soc. Chem. Commum. 965 (1992).
Wu, W., Zhang, J., Han, B., Chen, J., Liu, Z. Jiang, T., He, J., and Li, W., “Solubility of room-temperature ionic liquid in supercritical CO2 with and without organic compounds, Chem. Commun. 1412-1413 (2003).
23
Yanes, E.G.; Gratz, S.R.; Baldwin, M.J.; Robison, S.E.; Stalcup, A.M. Anal. Chem. 73, 3838 (2001).
Yoshizawa, M., W. Ogihara, and H. Ohno, “Novel Polymer Electrolytes Prepared by Copolymerization of Ionic Liquid Monomers”, Polymers for Adv. Technol., 2002, 13, 589.
Zakeeruddin, S. and Gratzel., M. 2002. Chemical Communications, 2972.
Zhang, H., K. Hong, M. Jablonsky, and J. W. Mays, “Statistical Radical Copolymerization of Styrene and Methyl Methacrylate in a Room Temperature Ionic Liquid”, Chem. Commun. 2003, 1356.
Zhang, H., K. Hong, and J.W. Mays, "Synthesis of Block Copolymers of Styrene and Methyl Methacrylate by Conventional Free Radical Polymerization in Room Temperature Ionic Liquids," Macromolecules, 35, 2002, 5738.
Zhang, S. and Zhang, Z.C. 2002. “Selective sulfur removal from fuels using ionic liquids at room temperature”, ACS Symposium Division of Fuel Chemistry, 47(2), 449-451.
Zhang, T.-F., Qiao, C.-Z., Zhang, J.-C. and Li, C.-Y. 2003. Research progress of environmentally friendl ionic liquid catalysts”, Huaxue Fanying Gongcheng Yu Gongyi 19(2), 164-170.
Zhao DB, Wu M, Kou Y, Min E. 2002. “Ionic liquids: applications in catalysis,” Catalysis Today
74 (1-2), 157-189.
Zhao, Y.-L., J.-M. Zhang, J. Jiang, C.-F. Chen, and F. Xi, “Atom Transfer Radical Copolymerization of N-hexyl maleimide and Styrene in an Ionic Liquid”, J. Polym. Sci., Part A: Polym. Chem., 40, 2002, 3360.
Zhao, Y.-L., C. F. Chen, and F. Li, “Living/Controlled Radical Copolymerization in an IL”, J. Polym. Sci., Part A-Polym. Chem., 2003, 41, 2156.
Zimmermann, J., Wasserscheid, P., Tkatchenko, I. and Stutzmann, S. 2002. “Biphasic dimerisation of methacrylate – immobilisation and stabilisation of cationic Pd-catalysts in ionic liquids by the ammoniumphosphine ligand”, Chemical Communications, in press.
Zulficar, F. and Kitazume, T. 2000. Green Chemistry 2, 137.
24
Patents and patent applications (US unless otherwise noted)
Catalysis 4,554,383 Knifton, J.F. , (Texaco) “Process for producing p-tolualdehyde from toluene using an aluminum halide alkyl pyridinium halide “melt” catalyst” 6,339,182 “Separation of olefins from paraffins using ionic liquid solutions” 5,994,602 Abdul-Sada, A.K., Atkins, M.P., Ellis, B., Hodgson, P.K.G., Morgan, M.L.M., Seddon, K.R, (BP Chemicals, Inc.) “Alkylation process” 5,304,615 (BP Chemicals) - butene polymerization using pyridinium or imidazolium chloride combined with an alkylaluminum halide, RnAlX3-n as the room temperature ionic liquid.
5,824,832 (Akzo Nobel) - assigned to describe a process for linear alkylbenzene formation using proprietary room temperature ionic liquids as described in U.S. Pat. No. 5,731,1091 that are made with alkyl amine hydrohalide salts combined with a metal halide.
5,220,106 (Exxon) - assigned to disclose a process using an ionic liquid to extract aromatics from a mixed hydrocarbon in which the preferred salt is triethylammonium dihydroxybenzoate.
6,103,908 Bahrmann, H. and Schulte, M. (Celanese GmbH) “Nonaqueous ionic liquids, process for preparing them and their use as catalyst constituents”
6,303,827 Saleh, R.Y., Becker, C.L., Michaelson, R.C., Schlosberg, R.H., (ExxonMobil Chemicals) “Process for making aromatic aldehydes”
6,395,948 Hope, K.D., Driver, M.S., Harris, T.V. (Chevron Chemical Company, LLC, USA) “High viscosity polyalphaolefins prepared with ionic liquid catalyst” (20020128532)
2002010291 Murphy, V. (Symyx Technologies, Inc, USA, Bayer, A.-G.) “Ionic liquids and processes for production of high molecular weight polyisoolefins” (WO20000032658. EP1144468)
2002050136 Boussand, B., Bonnet, P., Court, F., Devic, M., Hidalgo, M, Navarro, C. (Atofina, France) “Hydrogenation method for unsaturated block copolymers and hydrogenated unsaturated block copolymers” (FR281650, AU2002022030)
2002198100 Mehnert, C.P. and Cook, R.A. (ExxonMobil Research and Engineering Company, USA) “Supported ionic liquid membranes”, (WO2002098560)
2003050507 Couturier, J.-L. and Guerret, O. (Atofina, France) “Method for preparing alkoxyamines from nitroxides” (WO2002012149, FR2812639, EP1311472)
WO2002012171 Song, C.-E., Roh, E.-J. and Oh, C.-R. (Korea Institute of Science and Technology) “Method for preparing chiral compound by asymmetric ring opening reactions of epoxides” (AU2002029148).
WO2002034722 Chauvin, Y., Magna, L., Niccolai, G.P. and Bassett, J.-M. (Centre National de al Recherche Scientifique (CNRS) France), “Imidazolium salts and their use of these ionic liquids as a solvent” (EP1201657, EP1328518, AU2002010819)
WO2002030852 Earle, M.J. and Katdare, S.P. (The Queen’s University of Belfast, UK) “Oxidative halogenation of aromatic compounds n the presence of an ionic liquid” (AU2001095711, EP1324965)
WO2002030862 Earle, M.J. and Katdare, S.P. (The Queen’s University of Belfast, UK) “Oxidation of alkylaromatics in the presence of ionic liquids” (AU2001093968, EP1324968)
WO2002030865 Earle, M.J. and Katdare, S.P. (The Queen’s University of Belfast, UK) “Aromatic nitration reactions in ionic liquids” (AU2001093970, EP1324973)
25
WO2002030878 Earle, M.J. and Katdare, S.P. (The Queen’s University of Belfast, UK) “Aromatic sulfonation reactions conducted in the presence of ionic liquids” (AU2001093969,EP1324982)
WO2002079269 Mays, J.W., Bu, L., Rogers, R.D., Hong, K. and Zhang, H. (Uab Research Foundation, USA) “Polymer formation in room temperature ionic liquids”.
WO2003002502 Mehnert, C.P., Dispenziere, N.C. (ExxonMobil Research and Engineering Company, USA, Schlosberg, R.J.) “Process for conducting aldol condensation reactions in ionic liquid media, particularly imidazolium and pyridinium salts”
WO2003002579 Ignatyev, N., Schmidt, M., Kuehner, A., Hilarius, V., Heider, U, Kucheryna, A., Sartori, P. and Willner, H. (Merck patent Gmbh, Germany), “Synthesis, properties, and uses of (perfluoroalklyl)phosphorane-based novel strong acids and acid salts as catalysts, solvents, ionic liquids, and battery electrolytes”. (DE10130940)
WO2003020683 Ramani, A., Earle, M.J. and Robertson, A.J. (Cytec Technology Corp., USA, Seddon, K.R.) “Mononitration of aromatic compounds in phosphonium salt ionic liquids”.
WO2003057871 Kim, M.-J. and Lee, J.K. (Posco, S.Korea, Postech Foundation) “Preparation of ionic liquid-coated lipase and other enzymes with enhanced enantioselectivity for use in the chiral synthesis”
6,576,724 “Catalytic composition and process for the catalysis of dimerization codimerization and oligomerization of olefins”
6,501,001 “Process for selective dimerization of propylene principally into branched dimers”
6,469,216 “Process for hydroformylation using a catalyst based on cobalt and/or rhodium employed in a two-phase medium”
6,444,866 “Sequence of processes for olefin oligomerization”
6,410,799 “Hydroformylation process employing a catalyst based on cobalt and/or rhodium in a non-aqueous ionic solvent 6”
6,235,959 “Aliphatic hydrocarbon alkylation process”
6,028,024 “Catalytic composition and aliphatic hydrocarbon alkylation process”
2002052537 Commereuc, D., Forestiere, A., Hugues, F. and Olivier-Bourbigou, H. (Institut Francais du Petrole, France) “Sequence of processes for olefin oligomerization or dimerization or co-dimerization” (FR2815959, NL1019231, DE10152957,GB2369827)
2002099243 Favre, F., Commereuc, D and Olivier-Bourbigou, H. (Institut Francais du Petrole, France) “Process and apparatus for the hydroformylation of olefinically unsaturated compounds in a non-aqueous ionic solvent yielding aldehydes allowing for easy solvent and catalyst recycling” (FR2819806, EP1241156, JP2002275117)
WHERE 9847616 Ellis, B., Keim, W., Wasserscheid, P. “Oligomerisation catalyst comprising buffered ionic liquid” (Chem Abstracts 129:332457 1998)
WHERE2000016902 Germ, W., Korth, W., Wasserscheid P. (Chem Abstract 132:238691).
WHERE2000413 Germ, W., Ziegert, W., Wasserscheid, P. (Chem Abstacts 132:256580)
WHERE2000034311 Jones, M.D., Grimm, S., Keim, W., Wasserscheid, P. “Oligomerization of olefins by using catalysts containing complex of chromium compounds and 1,3,5-triazacyclohexane (Chem. Abstracts 133:45197 1999).
WHERE2000041809 Ellis, B., Hubert, F., and Wasserscheid, P. “Ionic liquid catalyst for alkylation” (Chem. Abstracts 133:107185)
26
DE19901524 Waffenschmidt, H., Wasserscheid, P., Keim, W. “Stabilization of homogeneous catalysts for recycle during distillative product separation using ionic liquid (Chem. Abstracts 133:121974 1999).
DE401417 von Voss, M., Wasserscheid, P. “Nonpolluting, biologically degradable…” (chem abstract 116:61895, 1990)
DE10003708 Boesmann, A., Wasserscheid, P., Bolm, C. and Germ, W. “New chiral ionic liquids and procedure for their representation in enantiomeric form”, application 2001.
DE-A10123467,8 Franco, G., Solinas, M., Janssen, Leitner, W., Boesmann, A, Wasserschmidt, P., Zimmermann, J., Ballivet-Tkatchenko, D., Piquet, M., Stutzmann, S. “Procedure for the immobilization and activation of cationic transition metal complexes using CO2..”
DE10127273 Koch, D., Schelhaas, M., Grotjohann, D. (Bayer AG, Germany) “Manufacture of polyamines of diphenylmethane series in presence of ionic liquids”
DE10129974,5 Boesmann, A. Datsevich, L., Jess, A., Lauter, A., Schmitz, C. and Wasserscheid, P., “Procedures for the removal of polarizable impurities from hydrocarbons and hydrocarbon mixtures by extraction with ionic liquids”, application published in February 2003.
DE 10155281 Wasserscheid, P., Boesmann, A., Jess, A., Datsevitch, L., Schmitz, C. and Lauter, A. (Solvent Innovation G.m.b.H., Germany), "Extractive method for eliminating polarizable impurities from hydrocarbons using ionic liquids as the extractants.” (WO2003037835)
FR 2,611,700 Chauvin, Y., Commereuc, D., Hirschauer, A., Hugues, F. and Saussine, L. 1988. “Process and catalyst for the dimerization or co-dimerization of olefins”
Patent applications
20010004972 Miller, S.J., O’Rear, D.J., Harris, T.V., Krug, R.R. (Chevron) “Process for making a lube base stock from a lower molecular weight feedstock using at least two oligomerization zones”
20010006154 Krug, R.R. and O’Rear, D.J. “Process for making a lube base stockfrom a lower molecular weight feedstockin a catalystic distillation unit”
20010039363 Hillebrand, G., Hirschauer, A., Commereuc, D., Olivier-Bourbigou, H. and Saussine, L. (Institut Francais du Petrole, France) “Process for hydroformylation using a catalyst based on cobalt and/or rhodium employed in a two-phase medium”
20010044550 Kenneally, C.J. and Connor, D.S. (The Procter and Gamble Company) “Process for the branching of saturated and/or unsaturated fatty acids and/or alkyl esters thereof”
20020010291 Murphy, V. (Symyx Technologies Inc) “Ionic liquids and processes for production of high molecular weight polyisoolefins”
20020091281 Chauvin, Y., Magna, L., Niccolai, G.P. and Basset, J.-M. (Celanese Chemicals Europe GmbH) “Process of telomerizing conjugated dienes”
20020099243 Favre, F.., Commereuc, D. and Olivier-Bourbigou, H. (Institut Francais du Petrole, France) “Process for the hydroformylation of olefinically unsaturated compounds in a non-aqueous ionic solvent”
20020156211 Hlatky, G.C. and Nagy, S. “Single-site catalysts based on anionic thiopyran dioxide ligands”
20020169071 Sauvage, E., Valkenberg, M.H, De Castro-Moreira, C.P. and Hoelderich, W.R. “Immobilised ionic liquids”
20020183574 Dixon, J.T., Grove, J.J.C, and Ranwell, A. “Hydrocarbon conversion process”
27
20020198100 Mehnert, C.P. and Cook, R.A. (ExxonMobil Research and Engineering Company) “Ionic liquid compositions”
20020198391 Petersen, H. and Rock, M.H. “Method for the preparation of citalopram”
20030050507 Couturier, J.-L. and Guerret, O. “Method for prepararing alkoxyamines from nitroxides”
20030050512 Mehnert, C.P., Dispenziere, N.C. and Schlosberg, R.H. (ExxonMobil Research and Engineering Company), “Process for conducting aldol condensation reactions in ionic liquid media”
20030055299 Hillebrand, G., Hischauer, A., Commereuc, D., Olivier-Bourbigou, H. and Saussine, L. (Institut Francais du Petrole, France) “Catalyst based on cobalt and/or rhodium employed in a two-phase medium”
20030060359 Olivier-Bourbigou, H., Commereuc, D., Martin, O., Magna, L. and Pellier, E. Institut Francais du Petrole, France) “Composition of catalyst and solvent and catalysis processes using this composition”
20030078442 Petersen, H., Bogeso, K.P. and Holm, P. (H. Lundbeck A/S), “Crystalline base of citalopram”
20030109767 Vasina, T.V., Kustov, L.M., Ksenofontov, V.A., Zubarev, Y.E., Houzvicka, J. and Zavilla, J. “Process of paraffin hydrocarbon isomerization catalysed by ionic liquids”
20030149264 Wasserscheid, P., Keim, W., Bolm, C., and Boesmann, A. “Chiral ionic liquids”
Separations
6,339,182 Munson et al. (Chevron) “Separation of olefins from paraffins using ionic liquid solutions”
6,579,343 Brennecke, J.F. and Maginn, E.J. (Notre Dame) “Purification of gas with liquid ionic compounds” (US2002189444)
2002001674/2001045187 Uhlenbrock, S. “Chemical vapor deposition methods utilizing ionic liquids”.
2002070122 Wu, B., Reddy, R.G. and Rogers, R.D. (The University of Alabama, USA) “Production, refining and recycling of lightweight and reactive metals in ionic liquids”.
20030125599 Boudreau, L.C., Driver, M.S., Munson, C.L. and Schinski, W.L. (ChevronTexaco). “Separation of dienes from olefins using ionic liquids and metal salt complexing agents” (WO2003059483)
WO2003013685 Goulao Crespo, J.P.S. and Schaefer, T. (Instituto de Biologia Experimental e Tecnologia (IBET), Port.). “Removal and recovery of solutes present in ionic liquids by pervaporation”.
WO2003039719 Wasserscheid, P., Kragl, U and Kroekel, J. (Solvent Innovation Gmbh, Germany), “Method for separating substances from solutions containing ionic liquids by means of a membrane).
DE10136614 Arlt, W. Seiler, M., Jork, C. and Sneider, T. (BASF Aktiengesellschaft, Germany) "Ionic liquids as selective additives for the separation of close-boiling or azeotropic mixtures" (WO2002074718)
DE 10154052 Gmehling, J. and Krummen, M. "Use of ionic liquids as entraining agents and selective solvents for separation of aromatic hydrocarbons in aromatic petroleum streams" (Chem. Abstracts 2003:527340)
DE 10154209 Wasserscheid et al. (Solvent Innovation G.m.b.H., Germany) "Method for separating substances from solutions containing ionic liquids by means of a membrane"
28
WO 2003013685 Crespo & Schaefer (Instituto de Biologia Experimental e Tecnologia, Portugal) "Removal and recovery of solutes present in ionic liquids by pervaporation".
WO 2003039719 Wasserscheid et al. (Solvent Innovation G.m.b.H., Germany) "Method for separating substances from solutions containing ionic liquids by means of a membrane", DE 10154209
Patent applications
20020189444 Brennecke & Maginn (Notre Dame) "Purification of gas with liquid ionic compounds"
20020070122 Wu et al (University of Alabama) "Production, refining and recycling of lightweight and reactive metals in ionic liquids (electrorefining of aluminum)”
Fuels 6,190,542 Catalytic multi-stage process for hydroconversion and refining hydrocarbon feeds 6,139,723 Iron-based ionic liquid catalysts for hydroprocessing carbonaceous feeds 6,274,026 Schucker and Baird (ExxonMobil) "Electrochemical oxidation of sulfur compounds in naphtha using ionic liquids" . 6,288,281 Direct carbonylation of paraffins using an ionic liquid catalyst 6,338,788 Schucker, R.C. (ExxonMobil Research and Engineering Company) “Electrochemical oxidation of sulfur compounds in naphtha” 6,350,721 Fu, D. and Card, R.J. (Schlumberger Technology Corporation) “Matrix acidizing fluids for petroleum wells containing super acids or mineral acids in the presence of ionic liquids” (WO2000032711, EP1163310, NO2001002689)
6,398,936 O’Rear, D.J., Harris, T.V., Miller, S.J., Krug, R.R. and Lok, R.K. “Manufacture of lubricating base oils from highly paraffinic feedstocks by alkane dehydrogenation and alkane oligomerization” (2002003102)
6,379,634 Fields et al. (British Nuclear Fuels PLC) “Ionic liquids as solvents dissolving in an ionic liquid by oxidation; application to dissolution of nuclear fuel”
6,468,495 , Fields, M, Thied, R.C., Seddon, K.R., Pitner, W.R., Rooney, D.W. (British Nuclear Fuels PLC), “Treatment of molten salt reprocessing wastes”
20030085156 Schoonover, R.E. “Method for extraction of organosulfur compounds from hydrocarbons using ionic liquids” (WO2003040264)
WO2002034863 O'Rear, D.J., Boudreau, L.C., Driver, M.S. and Munson, C.L. (Chevron USA) "Removal of mercaptans from hydrocarbon streams using ionic liquids" (AU2002016629)
WO2002066712 Bradley, A., Cogan, C.J., Hanson, B.C., Lewin, R.G., Ogden, M.D., Owens, S.L., Pitner, W.R., Rooney, D.W., Sanders, D., Smart, N.G., Taylor, R.J. and Thied, R.C. (British Nuclear Fuels PLC, UK) "Electro-refining process for separating metals".
Patent applications
20030091489 Hommeltoft, S.I. “Process for the drying of a hydrocarbon stream”
Other Energy Applications
5,683,832 Asulab S.A., Bonhote, P, Dias, A.-P., “Hydrophobic liquid salts, the preparation therof and their application in electrochemistry”
5,731,101 Akzo Nobel NV, Sherif, F.G., Shyu, L.-J., Lacroix, C.P.M., Talma, A.G., “Low temperature ionic liquids”
6,531,270 Olson, L.P. and Reynolds, J.H. (Eastman Kodak Company, USA), “Ionic liquids as coupler solvents in photothermographic systems”.
29
6,531,273 Olson, L.P., Boettcher, J.W. and Reynolds, J.H. (Eastman Kodak Company, USA), “Dispersions of ionic liquids for photothermographic systems and methods of making such systems”.
6,552,843 Tench, D.M. and Warren, L.F.Jr. (Innovative Technology Licensing LLC, USA) “Reversible electrodeposition device with ionic liquid electrolyte”.
2001053472 Edlund, D.J. (Idatech, Llc, USA) “Fuel cell systesm containing nonaqueous electrolytes” (WO2001093362, EP1290747)
200207613P McEwan, A.B. and Koch, V.R. (Covalent Associates Inc., USA) “Nonflammable electrolytes for electrochemical systems” (WO2001093363)
2002191270 Lu, W., Mattes, B.R., Fadeev, A.G. and Qi, B. “Stable conjugated polymer electrochromic devices incorporating ionic liquids” (WO2002053808)
Synthesis
5,827,602 “Hydrophobic ionic liquids”
2002015883 Hilarius, V., Heider, U. and Schmidt, M. (Merck Patent GmbH, Germany) “Ionic liquids” (EP1160249, DE10026565, BR2001002084, JP2002187893, CN1326936)
2002015884 Schmidt, M., Heider, U., Geissler, W., Ignatyev, N., Hilarius, V. (Merck Patent GmbH, Germany) “Ionic liquids” (EP1162204, DE10027995, CN1327986, JP2002025610, BR2001002318)
20020161261 Bahrmann, H., Bohnen, H. (Celanese Chemicals Europe GmbH, Germany) “Preparation of ionic liquids and their use” (DE19919494, WO2000066597, EP1177199, AT223919)
2003080312 Seddon, K.R., Carmechael, A.J. and Earle, M.J. (Queen’s University of Belfast, UK) “Process for preparing ambient temperature ionic liquids” (WO2001040146, EP1233936, JP2003515573)
WO2001077081 Earle, M.J. and Seddon, K.R. (Queen’s University of Belfast, UK) “Preparation of imidazole carbenes and the use thereof for the synthesis of ionic liquids” (EP1268440)
WO2002079212 Robertson, A.J. and Seddon, K.R. (Cytec Technology Corp, USA) “Preparation of phosphonium phosphinate compounds for use as polar solvents”
WO2003022812 Wasserscheid, P., Boesmann, A. and Van Hal, R. “Preparation of organic ammonium and phosphonium sulfates as ionic liquids”.
WO2003048078 Bonwrath, W., Leveque, J.-M., Luche, J.-L. and Petrier, C. (Roche Vitamins Ag., Switzerland), “Production of ionic liquids”.
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source:
Technical Summaries on Ionic Liquids in Chemical Processing
Prepared for the Chemical Industry Vision 2020 Technology Partnership Workshop Barriers to Ionic Liquid Commercialization
August 22, 2003
http://www.chemicalvision2020.org/ionic_liquids.html
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