A recent blog post by Haldor Topsoe researcher Dr. Pablo Beato reports progress
in operando spectroscopy.
Quoting from his post …
I inherited the responsibility for the optical spectroscopy in Topsoe in 2010. Since then, I have been trying to further develop the methods and infrastructure to monitor our catalysts in dedicated reactors while they are actually working. This type of methodology is often called “operando spectroscopy” and has become a dedicated field in catalysis research. It is based on the idea that catalysts, and in particular the surface of catalysts, are very dynamic under reaction conditions, and, if we really want to understand the active state of a catalyst, we need to look at it while it is doing its job. That is of course easier said than done.
Ideally, we would use a conventional reactor, which is also used for lab-scale catalytic testing, and modify it to get access to the catalyst surface with an optical probe (a laser or other light source). However, in many cases we have to design new types of reactors that allow us to combine the catalytic testing with spectroscopy. The operando methodology is not limited to spectroscopy techniques related to catalysis, but also includes diffraction and microscopy techniques that are used to characterize functional materials while they are performing under realistic conditions.source: https://blog.topsoe.com/from-science-to-dollars-operando-methodology?utm_source=hs_email&utm_medium=email&utm_content=63186794&_hsenc=p2ANqtz-9dWKekMApNv9OCFgf6ExFvov7D-a-dc6ZDBKBSAHyPvlNHwOqAR3MI1vnBnxJHJftqouCgg8qQ3zbGnSXnuBhIzuDshA&_hsmi=63186794
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According to Wikipedia …
Operando spectroscopy is a class of methodology, rather than a specific spectroscopic technique such as FTIR or NMR. Operando spectroscopy is a logical technological progression in in situ studies. Catalyst scientists would ideally like to have a "motion picture" of each catalytic cycle, whereby the precise bond-making or bond-breaking events taking place at the active site are known; this would allow a visual model of the mechanism to be constructed. The ultimate goal is to determine the structure-activity relationship of the substrate-catalyst species of the same reaction. Having two experiments—the performing of a reaction plus the real-time spectral acquisition of the reaction mixture—on a single reaction facilitates a direct link between the structures of the catalyst and intermediates, and of the catalytic activity/selectivity. Although monitoring a catalytic process in situ can provide information relevant to catalytic function, it is difficult to establish a perfect correlation because of the current physical limitations of in situ reactor cells. Complications arise, for example, for gas phase reactions which require large void volumes, which make it difficult to homogenize heat and mass within the cell. The crux of successful operando methodology, therefore, is related to the disparity between laboratory setups and industrial setups, i.e., the limitations of properly simulating the catalytic system as it proceeds in industry.
source: https://en.wikipedia.org/wiki/Operando_spectroscopy
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TIP: Search Google® Scholar using the phrase Pablo beato haldor
Here is one of the results from the search …
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Exploring Scaling Relations for Chemisorption Energies on Transition‐Metal‐Exchanged Zeolites ZSM‐22 and ZSM‐5
Dr. Samira Siahrostami
Dr. Hanne Falsig
Dr. Pablo Beato
Dr. Poul Georg Moses
Prof. Jens K. Nørskov
Dr. Felix Studt
First published: 12 January 2016
|https://doi.org/10.1002/cctc.201501049
Abstract
Copper exchange on all the different T sites of ZSM‐22 and ZSM‐5 is considered and the chemisorption energies of dioxygen, OH, and O species are studied. We show that for different T sites the adsorption energies vary significantly. The oxygen adsorption energy on copper‐exchanged zeolites is quite similar to those of the most selective catalysts for oxidation reactions, that is, Ag and Au surfaces. The chemisorption energies of oxygen, carbon‐, and nitrogen‐containing species on different transition metals exchanged in ZSM‐22 are also investigated. The study covers three different oxidation states, that is, 1+, 2+, and 3+ for the transition‐metal exchanges. Scaling relations are presented for the corresponding species. Chemisorption of O scales with chemisorption of OH for all three considered exchanges, whereas there are essentially rough correlations for NH2 and N as well as CH3 and source: https://onlinelibrary.wiley.com/doi/full/10.1002/cctc.201501049
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Quoting from his post …
I inherited the responsibility for the optical spectroscopy in Topsoe in 2010. Since then, I have been trying to further develop the methods and infrastructure to monitor our catalysts in dedicated reactors while they are actually working. This type of methodology is often called “operando spectroscopy” and has become a dedicated field in catalysis research. It is based on the idea that catalysts, and in particular the surface of catalysts, are very dynamic under reaction conditions, and, if we really want to understand the active state of a catalyst, we need to look at it while it is doing its job. That is of course easier said than done.
Ideally, we would use a conventional reactor, which is also used for lab-scale catalytic testing, and modify it to get access to the catalyst surface with an optical probe (a laser or other light source). However, in many cases we have to design new types of reactors that allow us to combine the catalytic testing with spectroscopy. The operando methodology is not limited to spectroscopy techniques related to catalysis, but also includes diffraction and microscopy techniques that are used to characterize functional materials while they are performing under realistic conditions.source: https://blog.topsoe.com/from-science-to-dollars-operando-methodology?utm_source=hs_email&utm_medium=email&utm_content=63186794&_hsenc=p2ANqtz-9dWKekMApNv9OCFgf6ExFvov7D-a-dc6ZDBKBSAHyPvlNHwOqAR3MI1vnBnxJHJftqouCgg8qQ3zbGnSXnuBhIzuDshA&_hsmi=63186794
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According to Wikipedia …
Operando spectroscopy is a class of methodology, rather than a specific spectroscopic technique such as FTIR or NMR. Operando spectroscopy is a logical technological progression in in situ studies. Catalyst scientists would ideally like to have a "motion picture" of each catalytic cycle, whereby the precise bond-making or bond-breaking events taking place at the active site are known; this would allow a visual model of the mechanism to be constructed. The ultimate goal is to determine the structure-activity relationship of the substrate-catalyst species of the same reaction. Having two experiments—the performing of a reaction plus the real-time spectral acquisition of the reaction mixture—on a single reaction facilitates a direct link between the structures of the catalyst and intermediates, and of the catalytic activity/selectivity. Although monitoring a catalytic process in situ can provide information relevant to catalytic function, it is difficult to establish a perfect correlation because of the current physical limitations of in situ reactor cells. Complications arise, for example, for gas phase reactions which require large void volumes, which make it difficult to homogenize heat and mass within the cell. The crux of successful operando methodology, therefore, is related to the disparity between laboratory setups and industrial setups, i.e., the limitations of properly simulating the catalytic system as it proceeds in industry.
source: https://en.wikipedia.org/wiki/Operando_spectroscopy
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TIP: Search Google® Scholar using the phrase Pablo beato haldor
Here is one of the results from the search …
///////
Exploring Scaling Relations for Chemisorption Energies on Transition‐Metal‐Exchanged Zeolites ZSM‐22 and ZSM‐5
Dr. Samira Siahrostami
Dr. Hanne Falsig
Dr. Pablo Beato
Dr. Poul Georg Moses
Prof. Jens K. Nørskov
Dr. Felix Studt
First published: 12 January 2016
|https://doi.org/10.1002/cctc.201501049
Abstract
Copper exchange on all the different T sites of ZSM‐22 and ZSM‐5 is considered and the chemisorption energies of dioxygen, OH, and O species are studied. We show that for different T sites the adsorption energies vary significantly. The oxygen adsorption energy on copper‐exchanged zeolites is quite similar to those of the most selective catalysts for oxidation reactions, that is, Ag and Au surfaces. The chemisorption energies of oxygen, carbon‐, and nitrogen‐containing species on different transition metals exchanged in ZSM‐22 are also investigated. The study covers three different oxidation states, that is, 1+, 2+, and 3+ for the transition‐metal exchanges. Scaling relations are presented for the corresponding species. Chemisorption of O scales with chemisorption of OH for all three considered exchanges, whereas there are essentially rough correlations for NH2 and N as well as CH3 and source: https://onlinelibrary.wiley.com/doi/full/10.1002/cctc.201501049
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