Tuesday, June 30, 2009

Searching’s Second Cousin, Serendipity

Searching the Web for background information on the ExxonMobil SCANfining process, I ran across the following …

“Evolution Of Process Technology For FCC Naphtha Desulfurization: 1997 – 2003; An Example Of Technical Progress Induced By Environmental Regulation,” a report prepared by MathPro Inc। (http://www.mathproinc.com/) 2003.


I find it helpful for the insights it provides in the development of desulfurization technologies from the pilot stage to the commercial stage. In Table 1, for example, CDTech's CD Hydro, Exxon's SCANfining, IFP's Prime G and Mobil's OCTGAIN 125 are listed as "demonstrated" technologies, whereas CDTech's CD Hydro / CD HDS, Mobil's OCTGAIN 220, and UOP's ISAL are listed as "near-commercial" and Black & Veatch's IRVAD and Philips Petroleum's S Zorb G processes are listed as "developing."

Read the complete report at: www.mathproinc.com/pdf/2.1.3_FCCNaphDesulf.pdf)

You might also want to add Mathpro to your favorites.

ChemSystems

ChemSystems (http://www.chemsystems.com/) is another organization to add to your favorites. According to the ChemSystems Web …

“ChemSystems from Nexant, Inc. provides support to decision makers in the petroleum, chemical and petrochemical industries to improve their business performance. ChemSystems provides data, analysis, forecasts, training and planning tools that improve understanding and planning in the uncertain world of energy and chemicals.”

A search on the ChemSystems site for “desulfurization” resulted in the following hit, among others …

Novel Desulfurization Technologies
PERP00-S8 (Oct. 2002) - Price: US $5,000.00
The chemistry, process technology and economics of the latest approaches for dealing with stricter sulfur specifications in gasoline in the U.S. and Western Europe are assessed.
source:
.chemsystems.com

Friday, June 26, 2009

The Rat’s Maze of Copyright

Ever since the case of American Geophysical Union v. Texaco, Inc., 37 F.3d 881 (2nd Cir. 1994), corporate legal has been careful that their company does not become liable for copyright infringement, unintentional though it may be.

To get a taste of the complexities of copyright, take a look at Professional Fair Use after Texaco (http://www.utsystem.edu/OGC/IntellectualProperty/tex2.htm)

Here are a couple of excerpts …

“All professionals in the university community should be aware of an important case that may potentially affect the way we pursue scholarship and research. On October 28, 1994, the Second Circuit Court of Appeals affirmed the decision of New York's Southern District Court that Texaco's copying of journal articles by or for its scientists was an infringement of the copyright owners' exclusive rights … The court indicated that to the extent the Copyright Clearance Center provided Texaco various convenient and reasonably priced mechanisms for payment of fees for copying, the scope of fair use had been reduced … The case gives copyright owners a tremendous incentive to register with the Copyright Clearance Center or other such licensing entity”

During my tenure as a librarian for Aramco Services (Saudi Aramco), I administered a number of contracts for information products. All of them included provisions for copyright. All of them were different. Some contracts made it possible for anyone in the entire Saudi Aramco enterprise to access the product. Other contracts went to the other extreme, allowing only a handful of specific individuals access to the product. And then there was a whole range in between the two extremes.

Before you share articles you find when you search a product, consult with your corporate librarian, if there is one, to find out what is permissible under the contract. If your company does not employ a librarian, find out who in your company administers the contract for the product . If all else fails, contact the sales rep for the product.

You might also ask if the company maintains an agreement with the CCC - Copyright Clearance Center (http://www.copyright.com/)

Googling® for Desulf

If you have an iGoogle® page, you can add any Google search you create as a feed on your page। For example, if you wanted to follow recent desulfurization efforts associated with Saudi Aramco, you might enter the following search in the Google search box:

aramco desulfurization 2009

At the bottom of the results page, you will find …

“Stay up to date on these results”
• Create an email alert for aramco desulfurization 2009
• Add a custom section for aramco desulfurization 2009
• Add a news gadget for aramco desulfurization 2009

Click the third of the three options and voilà! You have a newsfeed for “aramco desulfurization 2009” on your iGoogle homepage।

By the way, I found an interesting article in Oil & Gas Journal called Saudi Aramco to stick with investment program, output rate, CEO says.

Here is one paragraph from the article …

"Saudi Aramco's investments include developing an "intelligent" field to maximize recovery; futuristic devices such as "res-bots," tiny robots inserted into reservoirs to continuously report conditions; carbon capture and storage, and pre-refining crude desulfurization, he continued. "All of these efforts will reduce environmental impacts while building on our experience with proven technologies and practices in a worldwide market," he said."

Read the complete article at: ।ogj.com/index/article-display/361341/s-articles/s-oil-gas-journal/s-weekly-washington-update/s-update/s-saudi-aramco-to-stick-with-investment-program-output-rate-ceo-says.html">http://www।ogj.com/index/article-display/361341/s-articles/s-oil-gas-journal/s-weekly-washington-update/s-update/s-saudi-aramco-to-stick-with-investment-program-output-rate-ceo-says.html

Hart Energy

Hart Energy (http://www.hartenergy.com/home.हटमल) publishes a number of highly targeted newsletters and magazines, such as Diesel Fuel News. ULSD – Ultra Low Sulfur Diesel – is a major focus of refiners these days, as increasingly stringent regulations begin to be implemented. A quick search on “desulfurization” produced the following article, among others.

Topsoe: Improved Catalyst Dispersion Cuts ULSD Hydrotreating Cost
--------------------------------------------------------------------------------

San Antonio, Texas – Haldor Topsøe first introduced “Brim” catalysts for ultra-low sulfur diesel (ULSD) hydrotreating five years ago – and with great success, judging by the “several hundred hydrotreaters” using this catalyst.

But the drive to cut costs for ULSD continues, which explains the latest generation “Brim” with improved catalyst dispersion on the carrier surface, as Topsøe distillate marketing manager Lars Skyum explained in a presentation to National Petrochemical & Refiners Association 2009 annual meeting here late last month.

“With this new technology Topsøe now offers both catalysts with the same activity as the first generation but at lower fill cost, as well as more active catalyst types,” Skyum said.

--------------------------------------------------------------------------------

Read the complete article at: http://www.worldfuels.com/TRIAL/MARKETING/DieselFuel_News/Content/1ae2e49a-8472-4ae7-981b-663755b13cae.हटमल

Thursday, June 25, 2009

Frost & Sullivan

Frost & Sullivan (www.frost.com) specializes in gathering and analyzing information in a number of areas of technology in order to enable major corporations to take advantage of growth opportunities created by technical breakthroughs. In the words of the Frost & Sullivan site …

“Frost & Sullivan employs more than 1700 analysts, growth consultants and visionaries in more than 30 global offices. We provide 2 critical services to our "partners" to support their growth strategies: Growth Partnership Services and Growth Consulting. The Growth Partnership Services (GPS) is a subscription based program which provides our clients with both disciplined based research to support the generation and evaluation of growth opportunities and strategies and career focused best practices to help them implement growth strategies at best practice levels. Our growth consulting program provides our clients with customized consulting to support them with a visionary understanding of their market, the development of growth strategies and diagnosing their company's growth strategy system.”

source: http://www.frost.com/prod/servlet/company-info.pag

One report of particular interest to anyone involved in desulfurization is …

Frost & Sullivan Research Service Published: 26 May 2004
Oil Refining Technologies--New Developments and Growth Opportunities (Technical Insights)
You can get an idea of the quality of the report by browsing the contents of Chapter 7 …

CHAPTER 7 - CLEANING UP: HYDROTREATING; DESULFURIZATION AND DEMETALLIZATION
New Technologies
Description and Introduction
Desulfurization
Demetallization
Trends
Hydrotreating
Technical Drivers and Challenges
Key Developments in Hydrotreating
Introduction

ExxonMobil SCANFining
Nebula: Akzo Nobel
UOP: Sulfur-X
GTC GT-DeSulf Process
UOP/PDVSA: ISAL Gasoline Desulfurization
BOC-Linde IsoTherming Process
Badger/SK HDS Pretreater
ExxonMobil OCTGAIN Process
Phillips S-Zorb
Axens Prime-D Diesel Desulfurization
JGC Gas Oil Ultra-Deep Desulfurization
Criterion: Centinel Hydroprocessing Family
Indian Oil Technologies: INDE Sweet
Virginia Tech: New HT Catalyst Ideas
UIUC: Sonochemistry Improves HT Catalysis
New Concepts
University of Southern California: Nanotech Filtration Concept
Penn State: Selective Sulfur Removal
UniPure: A Fresh Distillate Desulfurization Idea
Biodesulfurization

source: http://www.frost.com/prod/servlet/report-brochure.pag?id=D274-01-00-00-00

Stanford Research Institute

SRI International (http://www.sri.com/), not to be confused with Southern Research Institute (www.sri.org), is a Stanford University affiliated organization that you should add to your favorites.

To quote from their Energy & Environment page ...

===
Energy and Environment

SRI's Assisted Hydrothermal Oxidation (AHO) technology is used by Mitsubishi Heavy Industries in Japan to safely dispose of polychlorinated biphenyls (PCBs) from wastewater.

As the lifeblood of all industrial and technological societies, energy is one of our most fundamental needs. Our nation's goal to achieve energy self-sufficiency affects U.S. foreign, environmental, security, and economic policies. Developing new energy sources and exploiting existing ones more efficiently and cleanly are among the 21st century's greatest challenges.

SRI addresses this issue with a diversified, holistic approach that brings multiple disciplines together to work on a problem of staggering technological, economic, and political complexity. Our government and commercial clients worldwide benefit from our scientific expertise and practical know-how in a range of areas, from basic and applied research to developing and testing of advanced systems.

In the 1940s, SRI pioneered smog research in Los Angeles and hosted the first National Air Pollution Symposium. In the 1970s, our groundbreaking research into the environmental causes of lung diseases led to regulatory guidelines for air pollutants. In the 1980s, we demonstrated how chlorofluorocarbons (CFCs) contribute to the ozone hole, and developed protocols for the EPA’s regulation of pesticides.

Today, SRI is developing pioneering technologies and services in power generation, energy storage, infrastructure, and environment:

Power generation

Fuel cells: PEM (proton exchange membrane fuel cells, SOFC (solid oxide fuel cells), DCFC (direct carbon fuel cells)
Solar cells (Single and polycrystalline silicon, thin film, nano-composite)
Thermal Cycling Absorption Process (TCAP) technology
Thermomagnetometry (TMAG) technology
Thermionics
Fuel sensors (hydrocarbon, hydrogen), oxidants, emissions, etc.
Advanced materials (turbines, coatings, corrosion/erosion resistance, nuclear)
Electroactive polymer "artificial muscle" for vibration scavenging, polymer engines, more)
Combustion (catalysts, kinetics, monitoring)
Energy storage

Batteries (High-power, high-energy, super capacitor, NFE, fiber)
Hydrogen generation and storage
Advanced materials (High-strength, corrosion-resistant, impermeable, membranes, gas sorbants)
Infrastructure

Pipeline materials, fracture detection, safety, and monitoring
Fuel processing and sensors
Switching of wide bandgap materials
Safety: natural gas, hydrogen, nuclear, remote gas leak detection
Environment

Dinitramide salts for nontoxic oxidizers
Noise suppression/vibration control
Chemical and engineering processes
Handheld biological and chemical sensors
Optoelectronic systems
Hydrothermal technology
Hydrogen fuel generation, storage, and distribution
Waste destruction
Pollution abatement
Potable water production
Biodegradable materials
Ultrasensitive hazardous materials detection
Environmental impacts and site selection
Eco-effective product design
Carbon dioxide separation, sequestration, and reaction
Nitrous oxide, sulfur oxide sensing and removal
Fuel clean-up (sulfur, heavy metals)
Hazardous waste destruction: Assisted Hydrothermal Oxidation (AHO), hot water extraction, trace chemical detection

===

Wednesday, June 24, 2009

Southern Research Institute

Southern Research Institute (www.sri.org) conducts research in various technology arenas, including energy & environment. A quick search for "desulfurization" on their site results in, among other hits ...

===
Syngas Cleaning
Syngas Cleaning Hot-Gas Filtration Desulfurization, Tar Cracking, Ammonia Cracking
Trace Metal Capture Preparation and Characterization of Catalysts and Sorbents
PSDF Transport Gasifier Laboratory-Scale Gasifer

Desulfurization, Tar Cracking, Ammonia Cracking
Desulfurization

This table summarizes results of recent tar cracking tests at PSDF using various catalysts and operating temperatures.
Southern Research's experience in hot-gas desulfurization includes the evaluation of commercial and custom-developed sorbents based on zinc and iron formulations in the temperature range of 550 to 750°F. One of the commercial sorbents (Johnson-Matthey Puraspec) was used to achieve H2S levels in the ppb range for a slipstream evaluation of a fuel cell. We have also worked closely with DOE on the optimization of the RVS-1 and RVSLT-1 sorbents developed by DOE.

Tar and Ammonia Cracking
Southern Research's experience includes high-temperature cracking of tar and ammonia at 1650 to 1750°F using nickel-based catalysts and lower-temperature tar cracking at 800°F using modified FCC catalysts. A process for the destruction of ammonia is also being developed based on the use of "Reverse" Selective Catalytic Reduction at 700-800°F. In this process, nitrogen oxides are injected or generated in situ to react with the ammonia and convert it to nitrogen.

The table below shows target conversions of ammonia and tar-related compounds. Experimental conversions achieved at the Power Systems Development Facility are shown under the target conversions.
===

Add SRI to your favorites for future reference.

Sunday, June 14, 2009

Babel

A large percentage of the desulfurization research is published in the English language. However, if you are fluent in another language, Google® and Yahoo!® searches can help you find literature in that language, as well. Even other non-Western scripts like Arabic can be searched.

The first step you might want to take is to go to a translation site like World Star Free Online Machine Translators (http://www.stars21.com/translator/).

The Arabic for desulfurization, for example, is …

الكبريت
إزالة

Copy the Arabic script to your clipboard, then paste into the Google® or Yahoo!® search box, and the results will be Arabic language items pertaining to desulfurization.

Saturday, June 13, 2009

Research in Action: Trans Ionics Corporation

Trans Ionics Corporation (http://www.transionics.com/) looks to be an enterprise worth a second look. I ran across the name in an article called “Top-10 Most Promising ‘Clean Tech’ Companies Revealed" (http://www.hartfuel.com/1108/f.top10cleantech.html) which led me to The Rice Alliance for Technology and Entrepreneurship (http://www.alliance.rice.edu/alliance/). The Rice Alliance sponsors The Rice Alliance Technology Venture Forums, which, according to its site, “are some of the largest technology venture forums in North America. Representatives from emerging technology companies showcase their new ventures in front of investors and venture capitalists, industry representatives, business leaders, advisors, mentors, service providers and entrepreneurs. The Rice Alliance holds four Technology Venture Forums a year – one each in energy/clean tech, information technology/Web 2.0, nanotechnology, and life science.”

I followed a link to a “company directory” (http://www.alliance.rice.edu/alliance/Company_Directory.asp?SnID=2) which included a description of the company …

“Trans Ionics Corp. —Trans Ionics is developing a desulfurization process that removes sulfur from petroleum streams, including diesel fuel, to meet government mandated diesel sulfur specifications for fueling on and off-road diesel-powered vehicles.”

A patent search on Trans Ionics produced the following recent patent:
Title:
Process for desulfurization of hydrocarbons
US Patent 7527724
Abstract:
The present invention is a method of removing sulphur from a hydrocarbon feed stream, comprising the steps of:
(a) dissolving sodium in a liquid solvent to form a solution containing sodium atoms;
(b) combining the liquid solution from step (a) with a liquid hydrocarbon feed containing an organosulfur component to form a combined stream at a temperature of addition and at a pressure near or above the vapor pressure of the solvent at the temperature of addition;
(c) reacting the combined stream for sufficient reaction time and at sufficient reaction temperature to form a modified composition comprising one or more sulfur-containing species and less of the organosulfur species than had been present in the hydrocarbon feed;
(d) extracting a portion of the sulfur-containing species from the modified composition.
Inventor:
Schucker, Robert C. (The Woodlands, TX, US)
05/05/2009

Wednesday, June 10, 2009

Patents: What’s in a Name?

When you search for a patent assignee with two or more words in the name, use the following search statement as a guide. It is designed to search for BRITISH PETROLEUM’s patents pertaining to desulfurization OR dibenzothiophene.

SEARCH STATEMENT
(AN/"british petroleum" OR AN/bp) AND (SPEC/desulfurization OR SPEC/dibenzothiophene)

Note the use of parentheses around the two OR statements. With practice, you can create quite complex search statements to target just the patents you need for your purpose.

RESULTS
7252756
Preparation of components for refinery blending of transportation fuels
A process is disclosed for the production of refinery transportation fuel or components for refinery blending of transportation fuels having a reduced amount of sulfur and/or nitrogen-containing...

7491316
Preparation of components for refinery blending of transportation fuels
The process of the present invention involves reducing the sulfur and/or nitrogen content of a distillate feedstock to produce a refinery transportation fuel or blending components for refinery...

6872231
Transportation fuels
The present invention relates to Compositions of fuels for transportation are disclosed, particularly organic compositions which are liquid at ambient conditions. More specifically, it relates to...

7300476
Transportation fuels
The present invention relates to Compositions of fuels for transportation are disclosed, particularly organic compositions which are liquid at ambient conditions. More specifically, it relates to...

6673230
Process for oxygenation of components for refinery blending of transportation fuels
Economical processes are disclosed for production of components for refinery blending of transportation fuels which are liquid at ambient conditions by selective oxygenation of refinery feedstocks...

6827845
Preparation of components for refinery blending of transportation fuels
Economical processes are disclosed for the production of components for refinery blending of transportation fuels by selective oxidation of feedstocks comprising a mixture of hydrocarbons,...

6881325
Preparation of components for transportation fuels
Economical processes are disclosed for the production of components for refinery blending of transportation fuels by selective oxidation of feedstocks comprising a mixture of hydrocarbons,...

7052598
Process for the production of gasoline with a low sulfur content comprising a hydrogenation, a fractionation, a stage for transformation of sulfur-containing compounds and a desulfurization
A process for the production of gasoline with a low sulfur content that comprises at least one selective hydrogenation of diolefins, optionally at least one stage for transformation, preferably to...

6733660
Multistage process for removal of sulfur from components for blending of transportation fuels
Economical processes are disclosed for the production of fuels of reduced sulfur content from a feedstock, typically derived from natural petroleum, wherein the feedstock is comprised of limited...

6736963
Multiple stage process for removal of sulfur from components for blending of transportation fuels
Economical processes are disclosed for the production of fuels of reduced sulfur content from a feedstock, typically derived from natural petroleum, wherein the feedstock is comprised of limited...

6059962
Multiple stage sulfur removal process
A product of reduced sulfur content is produced in a multiple stage process from a feedstock which is comprised of a mixture of hydrocarbons and includes sulfur-containing aromatic compounds as...

7473349
Process for removal of sulfur from components for blending of transportation fuels
A process is disclosed for removing highly deletenious non-basic nitrogen compounds upstream from an acid catalyzed thiophene alkylation process using adsorbents capable of adsorbing the non-basic...

6024865
Sulfur removal process
A product of reduced sulfur content is produced from a feedstock which is comprised of a mixture of hydrocarbons and includes sulfur-containing aromatic compounds as unwanted impurities. The...

6048451
Sulfur removal process
A product of reduced sulfur content is produced from a feedstock which is comprised of a mixture of hydrocarbons and contains organic sulfur compounds as unwanted impurities. The process comprises...

6025534
Olefin polymerization process
A method is provided for regenerating a fixed bed of olefin polymerization catalyst which can be performed without taking the catalyst bed out of service. The method involves the use of two...

5914293
Absorbent and process for removing sulfur oxides from a gaseous mixture
A collapsed composition is described which is substantially composed of microcrystallites collectively of the formula: M 2m 2 + Al 2 -p M p 3 + T r O 7 +rs where M 2 + is a divalent metal, M...

6103103
Dehydrogenation catalyst and process
A process and catalyst are provided for dehydrogenating a hydrocarbon feedstock and producing an olefinic product. The process comprises contacting the feedstock at dehydrogenation conditions with...

6197717
Dehydrogenation catalyst and process
A process and catalyst are provided for dehydrogenating a hydrocarbon feedstock and producing an olefinic product. The process comprises contacting the feedstock at dehydrogenation conditions with...

7374667
Process for the production of gasoline with a low sulfur content comprising a stage for transformation of sulfur-containing compounds, an acid-catalyst treatment and a desulfurization
For the production of gasoline with a low sulfur content, a process comprises at least one stage for transformation of sulfur-containing compounds consisting of an alkylation or adsorption of...

6599417
Sulfur removal process
A product of reduced sulfur content is produced from an olefin-containing hydrocarbon feedstock which includes sulfur-containing impurities. The feedstock is contacted with an olefin-modification...

6602405
Sulfur removal process
A product of reduced sulfur content is produced from an olefin-containing hydrocarbon feedstock which includes sulfur-containing impurities. The feedstock is contacted with an olefin-modification...

7541502
Components for blending of transportation fuels
Disclosed are fuel compositions for internal combustion engines comprising as a predominant component organic distillates which exhibit suitable physical properties, and a low-sulfur fraction of an...

7473351
Removal of nitrogen, sulfur, and alkylating agents from hydrocarbon streams
The present invention provides a process for reducing the nitrogen content of a liquid hydrocarbon feed wherein said process comprises a) contacting a liquid hydrocarbon feed comprising an...

7300568
Method of manufacturing oxygenated fuel
Disclosed is a process to improve the cetane number and emissions characteristics of a distillate feedstock by increasing the oxygen content of the feedstock by contacting the feedstock with an...

7074322
System and method for liquefying variable selected quantities of light hydrocarbon gas with a plurality of light hydrocarbon gas liquefaction trains
An improved system and method for providing reduced acid gas/dewatered light hydrocarbon gas to a light hydrocarbon gas liquefaction process wherein a plurality of light hydrocarbon gas...

6953488
Preparing synthesis gas using hydrotalcite-derived nickel catalysts
There is provided a process for preparation of synthesis gas from feedstocks containing methane and/or higher hydrocarbons having from about 2 to about 12 carbon atoms by an initial catalytic...

7168265
Integrated processing of natural gas into liquid products
An integrated process for producing LNG and GTL products is provided, wherein a CO 2 -containing natural gas feed to an LNG production zone is first pre-treated to separate at least a portion of...

6743829
Integrated processing of natural gas into liquid products
An integrated process for producing LNG and GTL products is provided comprising cooling natural gas in at least one cooling step so as to provide a cooled natural gas stream; processing the cooled...

6695983
Syngas production method utilizing an oxygen transport membrane
A method of producing a crude syngas product stream or a syngas product stream by further processing of the crude syngas product stream. Both the crude and syngas product stream comprise carbon...

Patents on FreePatentsOnline

Another advantage to searching for patents on a service like FreePatentsOnline (http://www.freepatentsonline.com/) is that viewing the full patent, including images, is much easier than on the USPTO site. Searching for recent Conoco Phillips patents with the key words desulfurization OR dibenzothiophene resulted in one hit, shown below. By clicking on the hyperlink, the full text of the patent came up. By logging into your free FreePatentsOnline account, you can pull up the images, as well.

SEARCH STATEMENT
AN/conoco$ and (SPEC/desulfurization OR SPEC/dibenzothiophene) and ISD/1/1/2005->6/1/2009

RESULTS
7182918
Desulfurization process A hydrocarbon desulfurization system that circulates fluidizable solid particles through a fluidized bed reactor, a fluidized bed regenerator, and a fluidized bed reducer to thereby provide for...

Tuesday, June 9, 2009

Free the Patents

A pretty silly title, really. Patents are already free at the USPTO site. However, there are advantages to searching a site like FreePatentsOnline (http://www.freepatentsonline.com/). One advantage is the sheer speed of the search engine. When I searched the site for recent ChevronMobil patents containing the key words DESULFURIZATION or DIBENZOTHIOPHENE, it took me longer to type in the search statement (below) than it took the search engine to return the results (reproduced below).

SEARCH STATEMENT
AN/chevron$ and (SPEC/desulfurization OR SPEC/dibenzothiophene) and ISD/1/1/2005->6/1/2009

RESULTS
7537685
Hydrocarbon conversion using molecular sieve SSZ-71
The present invention relates to new molecular sieve SSZ-71 prepared using a N-benzyl-1,4-diazabicyclo[2.2.2]octane cation as a structure-directing agent, methods for synthesizing SSZ-71 and...

7527778
Zinc-containing zeolite with IFR framework topology
A process is disclosed for preparing a zinc-containing molecular sieve having IFR framework topology and having zinc atoms in its crystal framework, said process comprising: (a) preparing an...

7500517
Kerogen extraction from subterranean oil shale resources
The present invention is directed to methods for extracting a kerogen-based product from subsurface (oil) shale formations, wherein such methods rely on fracturing and/or rubblizing portions of...

7459073
Hydrocarbon conversion using molecular sieve SSZ-47B
The present invention relates to new crystalline molecular sieve SSZ-47B prepared using a N-cyclopentyl-1,4-diazabicyclo[2.2.2] octane cation as a structure-directing agent and an amine too large...

7173160
Processes for concentrating higher diamondoids
Hydroprocessing such as hydrocracking is advantageously employed in processes for the recovery and purification of higher diamondoids from petroleum feedstocks. Hydrocracking and other...

7144497
Blending of low viscosity Fischer-Tropsch base oils with conventional base oils to produce high quality lubricating base oils
A process for producing a lubricating base oil blend which comprises (a) recovering a Fischer-Tropsch derived distillate fraction characterized by a kinematic viscosity of about 2 cSt or greater...

7141709
Methods and systems of producing monoolefins by the extraction-hydrogenation of highly unsaturated hydrocarbons
In some embodiments, methods of producing monoolefins include contacting an olefin stream with a polar solvent to extract a highly unsaturated hydrocarbon from the olefin stream, followed by...

7141157
Blending of low viscosity Fischer-Tropsch base oils and Fischer-Tropsch derived bottoms or bright stock
A process for preparing Fischer-Tropsch derived lubricating base oils by blending a Fischer-Tropsch distillate fraction having a viscosity of 2 or greater but less than 3 cSt at 100 degrees C. with...

7115198
Hydrocarbon conversion using molecular sieve SSZ-51
A novel crystalline aluminophosphate and metalloaluminophosphate of the molecular sieve type, denominated SSZ-51, is prepared by hydrothermal synthesis from reactive sources of aluminum and...

7083714
Hydrocarbon conversion using molecular sieve SSZ-65
The present invention relates to new crystalline molecular sieve SSZ-65 prepared using 1-[1-(4-chlorophenyl)-cyclopropylmethyl]-1-ethyl-pyrrolidini um or...

7074740
Catalyst for conversion processes
An improved catalyst for hydrodesulfurization of heavy feedstocks is disclosed. The catalyst is adopted for on-stream catalyst replacement in upflow processing units. It is characterized by a...
6962651
Method for producing a plurality of lubricant base oils from paraffinic feedstock
A method for producing lubricant base oils is provided comprising the steps of: (a) hydroisomerizing a feedstock over a medium pore size molecular sieve catalyst under hydroisomerization conditions...

6949180
Low toxicity Fischer-Tropsch derived fuel and process for making same
A method for preparing low toxicity Fischer-Tropsch fuels suitable for use in a diesel engine and Fischer-Tropsch derived fuel compositions having low toxicity suitable for use in diesel engines...

6911569
Sulfur resistant adsorbents
Sulfur resistant/tolerant adsorbents useful for separating olefins from paraffins in a cracked gas stream including hydrogen sulfide. The method comprises the steps of contacting the gaseous...
6908543
Method for retarding fouling of feed heaters in refinery processing
A method of minimizing the formation of polymers and other heavy molecular weight products upon heating of a hydrocarbon stream in a hydroconversion process is described. Specifically, sufficient...

6900365
Process for converting heavy hydrocarbon feeds to high octane gasoline, BTX and other valuable aromatics
A catalytic hydrodealkylation/reforming process which comprises contacting a heavy hydrocarbon feedstream under catalytic hydrodealkylation/reforming conditions with a composition comprising...

6881323
Hydrocarbon conversion using zeolite SSZ-54
The present invention relates to new crystalline zeolite SSZ-54 prepared using a templating agent comprising N-isopropyl ethylenediamine, or a mixture of 1-N-isopropyl diethylenetriamine and...

6878854
Temporary antioxidants for Fischer-Tropsch products
The present invention relates to the use of antioxidants in Fischer Tropsch derived products. The antioxidants of the present invention are preferably temporary antioxidants that may be removed...

6841063
Hydrocarbon conversion using zeolite SSZ-53
The present invention relates to a new crystalline zeolite SSZ-53 prepared by using phenylcycloalkylmethyl ammonium cations as structure directing agents.

6841062
Crude oil desulfurization
This invention relates to a crude oil desulfurization process which comprises hydrodesulfurizing a crude oil feed in a crude desulfurization unit. The desulfurized crude oil is then separated into...

Monday, June 8, 2009

Patent Searching on the Wild Side

Practice makes perfect, as they say, and nowhere is that more a propos than in searching for patents Here’s a quick example …

Let’s pretend that we are interested in all the patents for which ExxonMobil is the assignee (i.e., the owner).

Searching the USPTO database (http://patft.uspto.gov/) using the search phrase AN/ExxonMobil results in 1760 hits.

Searching the USPTO database using the search phrase AN/Exxon results in 6449 hits.

Searching the USPTO using the search phrase AN/Exxon$ (where “$” is a wildcard) results in 8224 hits.

You’ll notice that the wild card (“$”) enables us to retrieve patents issued where Exxon is the assignee OR where ExxonMobil is the assignee. And you will also notice that the whole is greater than the sum of the parts. Add 1760 + 6449 = 8209. Yet, the final wild card search strategy retrieves 8244.

Time for a walk on the wild side.

Sunday, June 7, 2009

Classy Patents

Perseverance in patent searching pays off in the long run. One tactic is to begin the search with a key word like “dibenzothiophene.” Explore the results of the search for patents of interest, and then do another search by the primary classification number(s) assigned to those patents. The result will be a list of patents that may also be of interest, even though they may or may not contain the key word of your initial search.

Example …
A search on the USPTO patent database (http://patft.uspto.gov/) using for patents issued in 2008 containing the keyword “dibenzothiophene” (SPEC/dibenzothiophene AND ISD/1/$/2008) results in seven hits, listed below.

PAT. NO. Title
1 7,321,012 Method of crosslinking intrinsically conductive polymers or intrinsically conductive polymer precursors and the articles obtained therefrom
2 7,320,955 Compositions comprising complexes of cyclodextrin and at least one laundry treatment active
3 7,320,849 Organophotoreceptor with a charge transport material having two epoxidated-hydrazone groups
4 7,318,966 Luminescent element material and luminescent element comprising the same
5 7,318,845
Compact distillates fuel processor with effective sulfur removal process
6 7,315,722 Image forming apparatus and image forming method
7 7,314,545 Desulfurization process

Clicking on item 5 reveals the following …

United States Patent 7,318,845 (January 15, 2008)
Compact distillates fuel processor with effective sulfur removal process
Abstract
A distillate fuel steam reformer system in which a fuel feed stream is first separated into two process streams: an aliphatics-rich, sulfur-depleted gas stream, and an aromatics- and sulfur-rich liquid residue stream. The aliphatics-rich gas stream is desulfurized, mixed with steam, and converted in a reforming reactor to a hydrogen-rich product stream. The aromatics-rich residue stream is mixed with air and combusted to provide heat necessary for endothermic process operations. Reducing the amounts of sulfur and aromatic hydrocarbons directed to desulfurzation and reforming operations minimizes the size and weight of the overall apparatus. The process of the invention is well suited to the use of microchannel apparatuses for heat exchangers, reactors, and other system components, which may be assembled in slab configuration, further reducing system size and weight.
--------------------------------------------------------------------------------
Inventors: Shaaban; Aly H. (Lynn Haven, FL), Campbell; Timothy J. (Parker, FL)
Assignee: Applied Research Associates, Inc. (Albuquerque, NM)
--------------------------------------------------------------------------------
Current U.S. Class: 48/61 ; 208/133; 208/208R; 208/213; 208/220; 208/308; 208/46; 208/49; 208/51; 208/57; 208/58; 208/67; 208/68; 208/69; 208/73; 208/78; 208/79; 208/80; 208/83; 48/127.9; 48/128; 48/211; 48/84

The primary U.S. Class number is listed first, in bold. Using that number to conduct a subsequent search, limited to a 2008 issue date (CCL/48/61 AND ISD/1/$/2008), reveals …

PAT. NO. Title
1 7,318,970 Architectural hierarchy of control for a fuel processor
2 7,318,846 Mixture formation means for a reformer of a fuel cell system or for a heater
3 7,318,845 Compact distillates fuel processor with effective sulfur removal process
4 7,316,718 Differential pressure-driven borohydride based generator


You can go on forever like this, or until your perseverance wears out.

Saturday, June 6, 2009

Patents: The Three P’s

Patents are a rich source of technological information. Mining the patent database effectively requires the three P’s … Practice, Persistence and Patience. If you have the time and the interest to see who is doing what in your field, get started by following the example below.

I went to the U.S. Patent & Trademark Office (USPTO) Web site (http://patft.uspto.gov/) and performed an advanced searchin the APPLICATIONS section of the database using this search strategy:

SPEC/dibenzothiophene AND SPEC/diesel

Of the 186 hits resulting from the search, the first 10 are listed below.

1 20090139898 Hydrogenation catalyst and use thereof
2 20090134067 SYSTEMS AND METHODS OF PRODUCING A CRUDE PRODUCT
3 20090134060 SYSTEMS AND METHODS OF PRODUCING A CRUDE PRODUCT
4 20090120842 Process for upgrading whole crude oil to remove nitrogen and sulfur compounds
5 20090120841 Methods of denitrogenating diesel fuel
6 20090107890 Desulfurization of whole crude oil by solvent extraction and hydrotreating
7 20090105966 Estimating detailed compositional information from limited analytical data
8 20090095683 PORTABLE FUEL DESULTURIZATION UNIT
9 20090084709 Method of producing low sulfur, high octane gasoline
10 20090076221 REMOVAL OF BRANCHED DIBENZOTHIOPHENES FROM HYDROCARBON MIXTURES VIA CHARGE TRANSFER COMPLEXES WITH A TAPA-FUNCTIONALIZED ADSORBENT

Opening each patent application in turn, I found the names of the organizations associated with each, as well as the primary patent classification code assigned to each, to wit …

20090139898 Hydrogenation catalyst and use thereof
Correspondence Name: KENYON & KENYON LLP
208/46


20090134067 SYSTEMS AND METHODS OF PRODUCING A CRUDE PRODUCT
Correspondence Name: SHELL OIL COMPANY
208/145


20090134060 SYSTEMS AND METHODS OF PRODUCING A CRUDE PRODUCT
Correspondence Name: SHELL OIL COMPANY
208/15


20090120842 Process for upgrading whole crude oil to remove nitrogen and sulfur compounds
Assignee Name: Saudi Arabian Oil Company
208/250


20090120841 Methods of denitrogenating diesel fuel
Assignee Name: UOP LLC
208/209

20090107890 Desulfurization of whole crude oil by solvent extraction and hydrotreating
Correspondence Name: ABELMAN, FRAYNE & SCHWAB
208/208R

20090105966 Estimating detailed compositional information from limited analytical data
Correspondence Name: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
702/30

20090095683 PORTABLE FUEL DESULTURIZATION UNIT
Correspondence Name: HONEYWELL INTERNATIONAL INC.
210/660

20090084709 Method of producing low sulfur, high octane gasoline
Assignee Name: Saudi Arabian Oil Company
208/250


20090076221 REMOVAL OF BRANCHED DIBENZOTHIOPHENES FROM HYDROCARBON MIXTURES VIA CHARGE TRANSFER COMPLEXES WITH A TAPA-FUNCTIONALIZED ADSORBENT
Correspondence Name: CHEVRON CORPORATION
525/102

When you do your search and identify a patent or patent application of interest, make a note of the patent classification code. Then repeat your search using the same code to see patents or patent applications that have been assigned the same code.

I will have more search tips in future posts to this blog.

Friday, June 5, 2009

Fine Print

Online databases like Ebsco’s Academic Search Complete help you keep on top of the technical literature in your area of interest. Here are a couple of tips to help you use Ebsco’s databases more effectively.

1) The Publications Tab. If you are particularly interested in a specific journal and want to find out if the Ebsco database includes it, click the Publications Tab. Then select the “Match Any Words” option and type a keyword of the journal title into the BROWSE box. For example, if the journal you are looking for has the word CATALYSIS in its title, type that into the search box and click the BROWSE button.

The resulting list looks something like this …

Applied Catalysis A: General
Bibliographic Records: 01/10/2002 to present

Applied Catalysis B: Environmental
Bibliographic Records: 01/10/2002 to present

Catalysis Communications
Bibliographic Records: 01/01/2002 to present

Catalysis Letters
Bibliographic Records: 01/01/2003 to present; Full Text: 01/01/2003 to present (with a 12 Month delay)
*Full text delay due to publisher restrictions ("embargo")
PDF Full Text

Catalysis Reviews: Science & Engineering
Bibliographic Records: 08/01/1998 to present; Full Text: 08/01/1998 to present (with a 18 Month delay)
*Full text delay due to publisher restrictions ("embargo")
PDF Full Text

Catalysis Surveys from Asia
Bibliographic Records: 06/01/2007 to present

Catalysis Today
Bibliographic Records: 01/15/2002 to present

Journal of Catalysis
Bibliographic Records: 01/01/2002 to present

Journal of Molecular Catalysis A: Chemistry
Bibliographic Records: 02/18/2002 to present

Journal of Molecular Catalysis B: Enzymatic
Bibliographic Records: 02/18/2002 to present

Kinetics & Catalysis
Bibliographic Records: 01/01/2003 to present; Full Text: 01/01/2003 to present (with a 12 Month delay)
*Full text delay due to publisher restrictions ("embargo")
PDF Full Text

Topics in Catalysis
Bibliographic Records: 01/01/2003 to present; Full Text: 01/01/2003 to present (with a 12 Month delay)
*Full text delay due to publisher restrictions ("embargo")
PDF Full Text

2) Read the fine print: Ebsco’s databases contain a combination of full text and non-full text resources. In the list above, for example, the Journal of Catalysis is represented only by Bibliographic Records, whereas Topics in Catalysis is represented both by Bibliographic Records AND by Full Text.

3) Note the dates: even when a journal is represented, the date range may not be sufficient for your needs. What’s more, many publishers allow inclusion of their journals on condition that the most recent issues are not included … the so-called “embargo” mentioned in a couple of the entries in the list above. So if it is important to you to be right up to the minute with a particular journal, you will need to find another source.

Thursday, June 4, 2009

Document Delivery Tip: EbscoHost

The Web is a great resource. I am a professional librarian, with a deep appreciation for the books housed by the thousands of libraries in the U.S. and beyond. But I love searching the Web, both for personal use and as a professional researcher.

There is a downside, however. I often identify an article of interest on the Web, but am unable to view the full text.

The first thing I do in this situation is to search for the same article in the various online databases at my disposal. If you work for a corporation with a site license to some of these databases, you should search them to see if the article you want is available through the site license.

If you are an independent consultant, you may not have access to these databases directly. In that case, try your public library.

For example, a Google© search on “dibenzothiphene” turned up the following article:

Deep Desulfurization of Diesel Fuel by Extraction with Task-Specific Ionic Liquids.Preview By: Liu, D.; Gui, J.; Song, L.; Zhang, X.; Sun, Z.. Petroleum Science & Technology, Jun2008, Vol. 26 Issue 9, p973-982, 10p, 4 charts, 1 diagram, 3 graphs; DOI: 10.1080/10916460600695496; (AN 32745488)

Searching Google© on the article title turned up no free full text source of the article.

So I logged onto my Houston Public Library account, searched for the title in EbscoHost, and was able to locate and download the full text of the article, thanks to HPL’s site license with Ebsco.

Contact your local public library to see what sorts of things they offer their users.

WorldCat

Libraries from all over the U.S. participate in a cooperative activity known as ILL – Interlibrary Loan. ILL enables libraries to provide document delivery service to their users. “Document delivery” includes obtaining copies of articles, and borrowing books.

So what does this mean to you, a desulfurization researcher? It means that your corporate librarian, if you have one, can obtain ON LOAN from another library a title such as the one below. If your company does not employ a librarian, or if you are an independent consultant, try your local public library. Houston Public Library, for example, provides access to WorldCat, which makes it easy to search for a key word like “desulfurization.”

Check, as we used to say when I was a kid, it out.

The desulfurization of heavy oils and residua
http://0-www.netlibrary.com.catalog.houstonlibrary.org/urlapi.asp?action=summary&v=1&bookid=39807
Author: Speight, J. G. Publication: New York : M. Dekker, 2000
Document: English : Internet Resource Computer File
Libraries Worldwide: 695

source: WorldCat

Tuesday, June 2, 2009

Do-it-yourself Bibliometrics

Bibliometrics, as I mention in an earlier post, can help pinpoint centers of research in a particular technical area. True bibliometrics requires vast bibliographic databases and sophisticated algorithms for analysis.

Sometimes, though, you can do seat of the pants bibliometrics that will suit your purposes just fine. For example, “Basic Research Needs: Catalysis for Energy (http://www.er.doe.gov/bes/reports/list.html),” a report from the U.S. Department of Energy Basic Energy Sciences Workshop, August 6-8, 2007, lists a number of “Workshop Participants,” each of whom is a significant figure in search for energy solutions. It also lists the organization each participant represents. By putting these two bits of information into a spreadsheet, I was able to sort and resort to reveal a number of possible avenues of research.

For example, although the bulk of participants represent the U.S. Government, it helps me to know which particular government organizations are most represented. Ditto for the university representatives.

Further, although the corporate participants typically only had one or two representatives, the fact that a corporate entity had any interest at all make it worth a second look.

If you would like a clean spreadsheet copy of the table below, send me an email request at: desulf@jeansteinhardt.com


ORGANIZATION NO. OF REPRESENTATIVES TYPE (Governmnet, University, Corporate)
U.S Department of Energy 16 G
Pacific Northwest National Laboratory 14 G
University of California, Berkeley 6 U
Argonne National Laboratory 5 G
Oak Ridge Institute for Science 4 G
Massachusetts Institute of Technology 4 U
Northwestern University 4 U
UOP, LLC 3 C
Brookhaven National Laboratory 3 G
Los Alamos National Laboratory 3 G
The Dow Chemical Company 2 C
Ames Laboratory 2 G
Idaho National Laboratory 2 G
Lawrence Berkeley National Laboratory 2 G
National Renewable Energy Laboratory 2 G
National Research Council, National Academy 2 G
National Science Foundation 2 G
Sandia National Laboratories 2 G
Savannah River National Laboratory 2 G
University of Delaware 2 U
University of Michigan 2 U
University of Notre Dame 2 U
University of Pennsylvania 2 U
University of Virginia 2 U
University of Washington 2 U
ABB Lummus Global 1 C
BP Group Technology 1 C
Brigham Young University 1 U
California Institute of Technology 1 U
Cornell University 1 U
Eindhoven University of Technology 1 U
Georgia Institute of Technology 1 U
Harvard University 1 U
Iowa State University 1 U
Pennsylvania State University 1 U
Purdue University 1 U
Rutgers, The State University of 1 U
SRI 1 U
Stanford Synchrotron Radiation Laboratory 1 U
Texas A&M University 1 U
Tufts University School of Engineering 1 U
Universität München 1 U
University of Alabama 1 U
University of California, Davis 1 U
University of California, San Diego 1 U
University of Colorado at Boulder 1 U
University of Kentucky Center for 1 U
University of Massachusetts at Amherst 1 U
University of Minnesota 1 U
University of Oklahoma 1 U
University of Rochester 1 U
University of Southern California 1 U
University of Texas 1 U
University of Texas at Austin 1 U
University of Wisconsin–Madison 1 U
University of Wyoming 1 U
Yale Universtiy 1 U
Catalytic Insights, LLC 1 C
Chemical & Engineering News 1 C
Eastman Chemical Company 1 C
ExxonMobil 1 C
Phillips Petroleum Company 1 C
RDS–Shell Global Solutions 1 C
U.S Department of Energy 16 G
U.S Department of Energy 16 G
U.S Department of Energy 16 G
U.S Department of Energy 16 G
U.S Department of Energy 16 G
U.S Department of Energy 16 G
U.S Department of Energy 16 G
U.S Department of Energy 16 G
U.S Department of Energy 16 G
U.S Department of Energy 16 G
U.S Department of Energy 16 G
U.S Department of Energy 16 G
U.S Department of Energy 16 G
U.S Department of Energy 16 G
U.S Department of Energy National 16 G
Pacific Northwest National Laboratory 14 G
Pacific Northwest National Laboratory 14 G
Pacific Northwest National Laboratory 14 G
Pacific Northwest National Laboratory 14 G
Pacific Northwest National Laboratory 14 G
Pacific Northwest National Laboratory 14 G
Pacific Northwest National Laboratory 14 G
Pacific Northwest National Laboratory 14 G
Pacific Northwest National Laboratory 14 G
Pacific Northwest National Laboratory 14 G
Pacific Northwest National Laboratory 14 G
Pacific Northwest National Laboratory 14 G
Pacific Northwest National Laboratory 14 G
University of California, Berkeley 6 U
University of California, Berkeley 6 U
University of California, Berkeley 6 U
University of California, Berkeley 6 U
University of California, Berkeley 6 U
Argonne National Laboratory 5 G
Argonne National Laboratory 5 G
Argonne National Laboratory 5 G
Argonne National Laboratory 5 G
Oak Ridge National Laboratory 4 G
Oak Ridge National Laboratory 4 G
Oak Ridge National Laboratory 4 G
Massachusetts Institute of Technology 4 U
Massachusetts Institute of Technology 4 U
Massachusetts Institute of Technology 4 U
Northwestern University 4 U
Northwestern University 4 U
Northwestern University 4 U
UOP, LLC 3 C
UOP, LLC 3 C
Brookhaven National Laboratory 3 G
Brookhaven National Laboratory 3 G
Los Alamos National Laboratory 3 G
Los Alamos National Laboratory 3 G
The Dow Chemical Company 2 C
Ames Laboratory 2 G
Idaho National Laboratory 2 G
Lawrence Berkeley National Laboratory 2 G
National Renewable Energy Laboratory 2 G
National Research Council, National Academy 2 G
National Science Foundation 2 G
Sandia National Laboratories 2 G
Savannah River National Laboratory 2 G
University of Delaware 2 U
University of Michigan 2 U
University of Notre Dame 2 U
University of Pennsylvania 2 U
University of Virginia 2 U
University of Washington 2 U