Sunday, October 31, 2010

Do Due Diligence

Diligence is a good thing, but taking things easy is much more restful” -- Mark Twain (American Humorist, Writer and Lecturer. 1835-1910)

An expert you may find useful is Dr. Amarjit Bakshi (abakshi@rhtgulfcoast.com), whom I found thanks to his contribution to a LinkedIn group I follow.

He has produced a number of patents, written articles for PTQ-Petroleum Technology Quarterly, Oil & Gas Journal, and Chemical Engineer, and is principal in a Texas based company named RHT-Refining Hydrocarbon Technologies (www.rhtgulfcoast.com)

As promising as all this seems, common sense dictates that you conduct some kind of background check before seriously considering a business arrangement.

Due diligence experts are available, but you can do a preliminary background check on your own, at no cost beyond your hourly rate.

Here is a checklist of free resources. You may be aware of most, if not all, but using a checklist helps you ensure a thorough check.

• Google (Miscellany)
• Google Scholar (Peer reviewed articles)
• Google Patents (Both granted and applied for)
• Obtain full text of articles (your librarian can help with this)
• Company’s Web
• LinkedIn (Read expert’s profile; note the groups he/she belongs to; is he/she connected to anyone you may know?)
• Remember to check your subscribed databases. Many organizations subscribe to LexisNexis, EbscoHost, and Dun & Bradstreet, among others

Squeeze the most value out of each item on your check list. For example, when you search for patents, study the results for …

• Inventors (associates)
• Assignee (company names)
• Abstract (key words and concepts)
• Referenced by (more associates; more company names)

Here are some results from a PRELIMINARY background check on Dr. Amarjit Bakshi.

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Publications
"Two phase flow and Natural Circulation Reboiler design", Chemical Engineer (UK) 1978 ''
"New route for MMA production " Oil & Gas Journal, 1986
"Visbreaker Design " Oil & Gas Journal, 1986
"Hydrogen Donor Visbreaking" oil and Gas Journal, 1987
"Why RHT Sulfuric Acid Alkylation", Presented at ERTC Annual conference 13-15 November, 2006
"New developments in Sulfuric acid alkylation" 2Q 2007 PTQ Magazine

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LinkedIn Profiles
Dr. Amarjit Bakshi, C.EngPresident at Refining Hydrocarbon Technologies LLC
Houston, Texas Area
President & CEO at Refining Hydrocarbon Technologies LLC
Past•Senior Manager , Refinery Advisor at Technip USA
•Director Strategic Business Development Refining Business area at GTC Technology LLP
•Senior Technology Manager/BD Executive at ABB LUMMUS GLOBAL INC
Consultannt at Jacobs see less...
Education•University of Surrey
•Scindia Public School
•University of Surrey
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Dr. Amarjit Bakshi, C.Eng’s Summary
RECENT Consultation Projects:with FUND Managers and others:
— Swedish Refining Industry
— Canadian Income Trust Model
— Design simulation software market
— North and South American oil exploration
— Refining technology solutions users
— Scandinavian refining industry
— Gas Transportation Infrastructure and
— Electrical energy transformer industry (
— Industrial Safety Technology Products
— Plant safety equipment and technology industry

Expert and innovative in all aspects of Refining and Petrochemical Busines including renewable fuels. Providing technology Licensing with smart configuaration to cut cost below 50 % of the present technologies.

Over 32 years experience in Engineering Management at senior level in Process Engineering, Technology, Operations and Project Management, Licensing, Acquisitions, Alliances and Business Development. Provided proven leadership and vision with broader perspectives and able to manage multiple tasks and personnel on mega projects. Significant Technology and process design and supervision experience in the field of refining including Crude/Vacuum units, Hydro Processing (All hydrotreating/ HDS and hydrocracking), FCC, Gas Plants, Alkylation, Reforming, and visbreaking including other Gasoline Processes e.g Iso-octene/Iso-octane and all units in Lube refining. ..Patents provide refiners and petrochemical plants innovations to enhance the performance of the units. Experience in safety audits, refinery optimization and heat integration/conservation studies.Worked in UK, Germany, Netherlands and USA, in a team environment and worked with multi cultural groups from North America/Japan/ Korea/China/Middle East/ Europe/ Russia/Iran etc. Experienced in business development in North America, Far East, India, middle East, Europe, Russia, Iran etc

Dr. Amarjit Bakshi, C.Eng’s Specialties:
Areas of interest:
1.. Refining Technology Options
2.CO2 Sequestration and other options
3.Advanced Technologies for Gas and Oil production from Shale/Oil Sands/Biomass .
4.Renewable Fuels, Ethanol from Cellulose, Biodiesel from Algae …
5.Operational Excellence of all Oil and Gas facilities,
6.Heavy Oil and Residue upgrading
7.Project development, Licensing , Catalyst selection, Basic and Process engineering,
8.New curriculum for Petroleum and Chemical Engineering
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Dr. Amarjit Bakshi, C.Eng’s Experience
President & CEO
Refining Hydrocarbon Technologies LLC
(Partnership; Oil & Energy industry)
January 2008 — Present (2 years 10 months)
Provide services to enhance the Client's economics and safety to provide solutions to the Refining and Petrochemical industry, technology/optimization/energy conservationand operations including Project Management/Process Engineeing/starts and turn arounds and enhancing organization and work force capability
Senior Manager , Refinery Advisor
Technip USA
(Public Company; TKP; Oil & Energy industry)
2006 — 2007 (1 year )
Provide leadership and expertise in Refining business together with Business development
Director Strategic Business Development Refining Business area
GTC Technology LLP
(Privately Held; Chemicals industry)
2005 — 2006 (1 year )
Senior Technology Manager/BD Executive
ABB LUMMUS GLOBAL INC
(Public Company; CBI; Oil & Energy industry)
1988 — 2005 (17 years )
Consultannt
Jacobs
(Public Company; JEC; Oil & Energy industry)
January 1986 — March 1987 (1 year 3 months)
Worked on Lube refining and Polyol projecsts
--------------------------------------------------------------------------------
Dr. Amarjit Bakshi, C.Eng’s Education
University of Surrey
Ph.D , Chemical Engineer , 1968 — 1973
Scindia Public School
High School ,
University of Surrey
Postgradute , Chemical Engineering
Activities and Societies:Chartered Engineer
C.Eng
--------------------------------------------------------------------------------
source: http://www.linkedin.com/in/rht2006
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LinkedIn Group Discussion
What would be good alternative for Delayed Coking Unit in a refinery scheme? Feedstock is vacuum residue or slurry from FCC.
Teymur = 2 months ago

Dr. Amarjit Bakshi, C.Eng • Stefan you are right as one wants from conversion process is product in gasoline/diesel or gas oil to get best ROI.
But the question is what the alternative to Delayed Coking is and I guess the premise is to lower in cost than Delayed Coker.
As we all know the most competitive refinery capacity is at least 300, 000 bbls/d refinery or higher. But all the refiners do not have financing capability to build refinery for that capacity and complexity also will drive the cost up. So Refiners have to build what they can afford not based only ROI.
But I think the question s what are alternative

Dr. Amarjit Bakshi, C.Eng • REINSERTED RESPONSE
Dr. Amarjit Bakshi • Most of the alternatives have been provided above in the comments from the experts. The major requirements after that one has to do the linear programming to look at the economics of the options. Even after the economics one has to look at the constraints of the financing and debt what the corporation is comfortable with.
Based on experience if financing/debt and cost control is major criteria, it can be easily point to certain options.
The Option of SDA and RESID FCC (if existing FCC can be revamped to high coke option) is a good one based on the required product slate. Otherwise still the other options are SDA and gasified where one can produce syngas and generate power, other option is to use syn gas to onvert to valuable fuel like diesel etc.
Another option is SDA and Coking operation with new technology of Rotary kiln technology which much simpler to operate.
As regards to Flexicoking it is site specific and normally not profitable and optimum technology except in exceptional case. This technology is offered by EXXONMOBIL and mostly used by them at about 6 or 7 refineries. One license was sold to Hellenic in 2008 and could be site specific or was not evaluated properly by the Hellenic as justification was not strong for low BTU gas. This also was very expensive option.
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GOOGLE PATENTS
Apparatus for conducting exothermic reactions
US Pat. 5792428 - Filed May 20, 1996 - Chemical Research & Licensing Company
Amarjit S. Bakshi; Timothy P. McGuirk; JC Gupta; Thomas Koval. all of Houston,
Tex. [73] Assignee: Chemical Research & Licensing Company. Pasadena, Tex. ...
Process for the preparation of ETBE
US Pat. 5248836 - Filed Oct 16, 1992 - Chemical Research & Licensing Company
28, [54] PROCESS FOR THE PREPARATION OF ETBE [75] Inventors: Amarjit Bakshi, The
Hague, Netherlands; Edward M. Jones, Jr., Friendswood; Bobby A. Strain ...

Etherification process
US Pat. 5919989 - Filed Jun 20, 1997 - Catalytic Distillation Technologies
6, [54] ETHERIFICATION PROCESS [75] Inventors: Amarjit Bakshi; Thomas P. Hickey,
both of Houston, Tex. [73] Assignee: Catalytic Distillation Technologies, ...

Method for conducting exothermic reactions
US Pat. 6335473 - Filed Sep 8, 2000 - Catalytic Distillation Technologies
... 2002 (54) METHOD FOR CONDUCTING EXOTHERMIC REACTIONS (75) Inventors: Amarjit
S. Bakshi; Timothy P. McGuirk; JC Gupta; Thomas Koval, all ol Houston, ...

Process for the production of gasoline stocks
US Pat. 7273957 - Filed Oct 29, 2004 - Catalytic Distillation Technologies
... United States Patent Bakshi et al. (io) Patent No. ... Jr 260/673 208/255
208/46 Inventors: Amarjit S. Bakshi, Houston, TX (US); Mitchell E. Loescher, ...

[APPLICATION] Process for ultra low sulfur gasoline
US Pat. 10295706 - Filed Nov 15, 2002 - CATALYTIC DISTILLATION TECHNOLOGIES
25, 2004 (54) PROCESS FOR ULTRA LOW SULFUR GASOLINE (75) Inventor: Amarjit S.
Bakshi, Katy, TX (US) Correspondence Address: KENNETH H. JOHNSON PO BOX ...

[APPLICATION] Sweet microwave popcorn product and method for production thereof
US Pat. 10475284 - Filed Mar 29, 2002
... CA (US); Amarjit S Bakshi, Yorba Linda, CA (US); Caroline Ponting, Yorka
Linda, CA (US) Correspondence Address: Gary D Lueck Bingham McCutchen Floor ...

[APPLICATION] Biodiesel process : RHT-Biodiesel
US Pat. 11540180 - Filed Sep 29, 2006 - Refining Hydrocarbon Technologies LLC
Date: Apr. 24, 2008 (54) BIODIESEL PROCESS : RHT-BIODIESEL (75) Inventor:
Amarjit Singh Bakshi, Katy, TX (US) Correspondence Address: AMARJIT SINGH BAKSHI

[APPLICATION] Multistage catalytic process for olefin etherification
US Pat. 11400846 - Filed Apr 10, 2006
Date: May, 2007 (54) MULTISTAGE CATALYTIC PROCESS FOR OLEFIN ETHERIFICATION (76)
Inventor: Amarjit Singh Bakshi, Katy, TX (US) Correspondence Address: ...

[APPLICATION] Low temperature low cost sulfuric acid alkylation process
US Pat. 11400845 - Filed Apr 10, 2006 - Refining Hydrocarbon Technologies LLC
... Al Bakshi (43) Pub. Date: Aug. 23, 2007 Novel Mixing Device Reactor details
... Katy, TX (US) Correspondence Address: AMARJIT SINGH BAKSHI REFINING ...

[APPLICATION] Low cost selective Octene process : RHT-Octene
US Pat. 11540179 - Filed Sep 29, 2006 - Refining Hydrocarbon Technologies LLC
Date: Apr. 3, 2008 RHT Octene Process (54) LOW COST SELECTIVE OCTENE PROCESS :
RHT-OCTENE (75) Inventor: Amarjit Singh Bakshi, Katy, TX (US) Correspondence ...

[APPLICATION] Low cost high yield Iso-octene/ Isooctane process with capability to revamp ...
US Pat. 11454044 - Filed Jun 15, 2006 - Refining Hydrocarbon Technologies LLC
... Al Bakshi (43) Pub. Date: Dec. 20, 2007 RHT Iso-Octene Process ... WITH
CAPABILITY TO REVAMP THE MTBE UNITS (75) Inventor: Amarjit Singh Bakshi, Katy,
...
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Jean Steinhardt Consulting LLC specializes in training the people in your organization to squeeze the maximum value from your subscribed databases. Follow the Desulfurization Blog (http://www.desulf.blogspot.com/) for more tips in how to maximize search effectiveness (and pass the word to friends and colleagues)

Wednesday, October 27, 2010

Revisiting a LinkedIn Discussion

“Friendship increases in visiting friends, but in visiting them seldom.” -- Francis Bacon, Sr. (English Lawyer and Philosopher. 1561-1626)

Not all LinkedIn groups are created equal. Some are little more than infomercials. Others are a mix. The Oil Refining Global Technology Forum is a mix. I have highlighted the following discussion in previous posts. Since then, the discussion has grown. I find it fascinating, so I am reproducing the most recent contributions below.

If you find value in the discussion, consider joining LinkedIn, and then join the Oil Refining Global Technology Forum.

When you get really inspired, contribute a comment to the discussion … and you may make some useful connections.

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Latest contribution to a LinkedIn Group discussion
Oil Refining: Global Technology Forum
source: http://www.linkedin.com/groupAnswers?viewQuestionAndAnswers=&discussionID=25931171&gid=1951256&trk=EML_anet_qa_ttle-cThOon0JumNFomgJt7dBpSBA

Teymur A., Senior Specialist (Refining/Petrochemicals) SOCAR, Azerbaijan, began the discussion with …

“What would be good alternative for Delayed Coking Unit in a refinery scheme? Feedstock is vacuum residue or slurry from FCC.”

Here are the responses …

Bill Howe • A niche solution might be to produce emulsion fuel as demonstrated at Mazeikiai refinery in 2008. Very low capital cost (<$50 million) which distinguishes it from other conversion technologies which run to hundreds of millions of dollars. Works on uncut vacuum residue allowing the cutter to be recovered to the fuel pool providing value add approaching a coker without the capital risk (an all liquid product solution - no low value coke). The niche issue is about finding a sink for the emulsion fuel.
Bill Howe
Independent Consultant
Bill Howe is the Chief Executive Officer at Quadrise Fuels International, a manufacturer of oil in water emulsions from refinery vacuum residues (and heavier). Quadrise sells a low cost equivalent to conventional HFO by establishing production facilities on refiner's sites. Benefits to the refiner are the ability to sell uncut vacuum residue to Quadrise at a price in excess of its intrinsic value as a fuel oil component; where its value is diminished by the need to add high value cutter-stock for viscosity control. Mr. Howe has more than 32 years of experience in the natural resources industry. Prior he was an Executive Director of Oil, Gas, and Energy at Bateman Projects, an EPC contractor; where he was responsible globally for oil, gas, water, and energy contracting operations. Mr. Howe has also worked as Director of Sales and Marketing at Foster Wheeler Energy Limited, an EPC contractor. He is knowledgeable on all commercial facets of the EPC contracting business and has specific experience around power generation, oil refining, GTL, residue emulsion fuel and water and waste engineering operations. Mr. Howe has knowledge on the process industries in South Africa where he was Managing Director of Foster Wheeler's local affiliate.
http://www.linkedin.com/profile/view?id=54186678&authType=name&authToken=cYIK&trk=anet_mfeed_profile
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Ron Wright
I think the answer would depend on what products you are trying to maximize and the quality of the vacuum resid you are working with. In general, you have carbon removal (delayed coking, resid FCC, visbreaking, solvent deashpalting) or hydrogen addition (Resid hydrotreating/hydrocracking ) options. They all have their place depending on the situation.
Ron

Rob Wong
One other to consider, in addition to Ron's excellent suggestions, is a fluid coker. However, you need to have a ready disposition for the byproduct low BTU gas.

Roger Haglund
Depends what product you are primarly interested in, and what Capext you can carry
For a diesel driven refinery and with a hydrocracker a coker is a good alternative but an alternative would be a gasifier with Hydrogen recovery (and Cogen) to run the hydrocracker. The latter solved the hydrogen issue and removes all residual products which the coker have to deal with. It also saves NG, LPG or naphtha from making hydrogen out of.

Stefan Romocki
All conversion processes have the same essential drivers; Revenue (a function of product quality and yield), Operating costs (energy consumed and other expenses such as catalyst), Capital (a function of capacity and complexity) while overall investment return is a product of net revenue over capex.
What we found is that liquid product yield is a major driver for the economics of conversion. Transportation fuels are subject to far less elastic pricing than gases, or heavy products. For example, while oil is $80 today, the price of natural gas (a proxy for refinery fuel gas) is only worth $27 on an energy equivalency basis. That implies within a conversion strategy it is best to minimize conversion to things which become gases and maximize conversion to liquids in the transport fuel boiling range.
If you would like to consider a contemporary conversion strategy, look at high conversion slurry hydrocracking. ENI's EST process is being built commercially at 23,000 bpd in Italy (2012) and offers up to 98% conversion. RIPI's HRH technology is unique in that it operates at mild hydrocracker pressure (70bar) but still offers 90-95% conversion relying on a very active hydrogenation catalyst. Both these processes recover and remanufacture catalyst within the process limits which reduces operating costs and increases run lengths. Most refinery licensing company now offer slurry processes, but our bias is towards the more active catalysts with lower gas and by-product yields.

Dr. Amarjit Bakshi, C.Eng
Stefan you are right as one wants from conversion process is product in gasoline/diesel or gas oil to get best ROI.
But the question is what the alternative to Delayed Coking is and I guess the premise is to lower in cost than Delayed Coker.
As we all know the most competitive refinery capacity is at least 300, 000 bbls/d refinery or higher. But all the refiners do not have financing capability to build refinery for that capacity and complexity also will drive the cost up. So Refiners have to build what they can afford not based only ROI.
But I think the question s what are alternative

Dr. Amarjit Bakshi, C.Eng • REINSERTED RESPONSE
Most of the alternatives have been provided above in the comments from the experts. The major requirements after that one has to do the linear programming to look at the economics of the options. Even after the economics one has to look at the constraints of the financing and debt what the corporation is comfortable with.
Based on experience if financing/debt and cost control is major criteria, it can be easily point to certain options.
The Option of SDA and RESID FCC (if existing FCC can be revamped to high coke option) is a good one based on the required product slate. Otherwise still the other options are SDA and gasified where one can produce syngas and generate power, other option is to use syn gas to convert to valuable fuel like diesel etc.
Another option is SDA and Coking operation with new technology of Rotary kiln technology which much simpler to operate.
As regards to Flexicoking it is site specific and normally not profitable and optimum technology except in exceptional case. This technology is offered by EXXONMOBIL and mostly used by them at about 6 or 7 refineries. One license was sold to Hellenic in 2008 and could be site specific or was not evaluated properly by the Hellenic as justification was not strong for low BTU gas. This also was very expensive option.

Attilio Donarelli
My personal opinion on the CONS of each alternative for the Bottom of the Barrel conversion. Still Coker seems to be the most cheap and cheerful solution
Slurry process - not tested commercially
Gasification and Power production - works mainly when the price of electricity is subsidised
SDA - not to couple with Hydrocraker only FCC
Ebullating bed vac residue hydroconversion - work better than in the past but sitll high capex and opex
Coker - what to do with the coke?
Flexicoker - Exxonmobil licensed 4 units to Exxon refineries, 1 in Venezuela and 1 in Greece. Total 6, does it mean anything?
RFCC - not for very high concarbon feeds

Mario Vanacore
at the present crude oil mkt situation (70-80 $/bbl and low margins) coker is certainly one of the most convenient conv technologies, at an higher crude oil price (let say around 100 $/bbl or even higher) other technologies become much interesting (Residue HDC, Ebullated bed, etc). Capex and Opex for all these type of unit are usually higher.

Dr. Amarjit Bakshi
Coming back to the question, if refiner does not have resources to put Delayed Coker which technologies he should consider if any. As I understand that is the question.
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Visit Jean Steinhardt’s LinkedIn Profile: www.linkedin.com/in/jeansteinhardtresearch ... then invite him to join your network.

Thursday, October 21, 2010

“You Can Quote Me” - ScienceDirect Search Tip

“Any time Detroit scores more than 100 points and holds the other team below 100 points, they almost always win.” — Doug Collins, head coach of the NBA's Philadelphia 76ers (source: http://lowposts.com/quotes/)

Imagine that you run across the following article …

Separation and Purification Technology
Improvement in Diesel Desulfurization Capacity by Equilibrium Isotherms Analysis
Huang Tanga, b, Wangliang Lia, , , Ting Zhanga, b, Qiang Lia, b, Jianmin Xinga and Huizhou Liua, c
wlli@home.ipe.ac.cn
a National Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, P.O. Box 353, Beijing 100190, China
b Graduate University of Chinese Academy of Sciences, Beijing 100049, China
c Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
Received 1 September 2009; revised 8 October 2010; accepted 8 October 2010. Available online 15 October 2010.
Abstract
Mesoporous Aluminosilicates (MAS) showed advantages over zeolites and mesoporous molecular sieves in adsorption desulfurization of diesel fuels. However, the adsorptive capacity still has great space to improve. The equilibrium adsorption data were modeled by Langmuir and Freundlich isotherms. Langmuir model can well describe the adsorption on ion-exchanged MAS. Infer from the hypothesis conditions of Langmuir model, the temperature and the active sites are two key factors to determine the adsorptive capacity. Adsorption experiments were carried out with both model oils and diesel fuels on fixed-bed. The results showed that π-complexation adsorbents were more efficient to remove sulfur compounds at higher temperature and that the saturated adsorption capacity had a linear relationship with the silver ions loaded on the adsorbents.
Keywords: Diesel fuels; Adsorption desulfurization; Mesoporous Aluminosilicates; Π-complexation
Source: www.ScienceDirect.com

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Now, imagine you would like to find other articles authored by Huang Tang, one of the authors of the above.

You enter Huang Tang in the ScienceDirect Author search box, and are presented with a list of 1494 articles.

Save yourself some time by entering the same search string ENCLOSED IN QUOTES, i.e.

"huang tang"

This results in just seven (7) hits … a much more manageable and useful list of articles. One of them is …

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Deep desulfurization of diesel by integrating adsorption and microbial method
Biochemical Engineering Journal, Volume 44, Issues 2-3, 15 May 2009, Pages 297-301
Wangliang Li, Huang Tang, Qingfen Liu, Jianmin Xing, Qiang Li, Dan Wang, Maohua Yang, Xin Li, Huizhou Liu
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Follow the Desulfurization Blog (http://www.desulf.blogspot.com/) for more time saving search tips.

Monday, October 18, 2010

More π complexation

Complex problems have simple, easy to understand, wrong answers.” -- Henry Louis Mencken (American humorous Journalist and Critic of American life, 1880-1956)
Finding full text
Despite the problems of duplication and irrelevance, searching for articles of interest is easier than it ever has been since the advent of written language. Finding the full text of those articles remains complex. Sure, if you have money to flagrate, you can buy for download at any site you find a referenced article. But if budget is a problem, you first want to find out if you have the full text available through your organization’s subscription to EbscoHost, ScienceDirect, or some other source.

Below are abstracts of several recent articles found by Googling for “π complexation”. In each case, you can, with a credit card, download the full text immediately. Usually, however, you and your organization are better served by asking your librarian to purchase it for you.

There are two (2) advantages to this, even if the library charges back the download cost to your unit
(1) Your information professional may be able to find a free source of the article
(2) Over time, the librarian will develop a sense of the most used sources for full text download, and will be able to identify lower cost vendors for those sources

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Recent π complexation articles
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Desulfurization of Gasoline over Nanoporous Nickel-Loaded Y-Type Zeolite at Ambient Conditions
Majid Dastanian and Fakhry Seyedeyn-Azad*
Chemical Engineering Department, Engineering Faculty, University of Isfahan, Isfahan, Iran
Ind. Eng. Chem. Res., Article ASAP
DOI: 10.1021/ie100941s
Publication Date (Web): October 11, 2010
Copyright © 2010 American Chemical Society
* To whom correspondence should be addressed. E-mail: fsazad@eng.ui.ac.ir or fsazad@hotmail.com.
AbstractDesulfurization of heavy straight-run gasoline (HSRG) was accomplished over Ni(II)−Y zeolite. Na−Y zeolite, a nanoporous adsorbent, was synthesized and ion-exchanged with NH4NO3 to obtain NH4−Y zeolite. The obtained material was then converted to H−Y zeolite by calcination. Ni−Y zeolite was prepared by solid-state ion exchange (SSIE) of H−Y zeolite using Ni(NO3)2•6H2O. The breakthrough curve for desulfurization of HSRG containing about 140 ppmw of sulfur compounds was obtained in a batch reactor at ambient conditions. The effects of temperature, Ni content in the zeolite framework, and aging of the zeolite on the desulfurization process were investigated. Ni−Y zeolite exhibited a high capability for the desulfurization of gasoline at ambient conditions.
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Adsorptive Desulfurization by Copper Species within Confined Space
Hang Tian, Lin-Bing Sun, Xue-Lin Song, Xiao-Qin Liu*, Yu Yin, and Gu-Se He
State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China
Langmuir, Article ASAP
DOI: 10.1021/la101856d
Publication Date (Web): September 30, 2010
Copyright © 2010 American Chemical Society
*Corresponding author. Telephone: +86-25-83587178; fax: +86-25-83587191; e-mail: liuxq@njut.edu.cn.
Abstract
Copper species were incorporated into SBA-15 by solid-state grinding precursor with as-prepared mesoporous silica (SPA). The obtained materials (CuAS) were well-characterized by XRD, TEM, N2 adsorption, H2-TPR, IR, and TG and compared with the material derived from calcined SBA-15 (CuCS). Surprisingly, CuO up to 6.7 mmol•g−1 can be highly dispersed on SBA-15 by use of SPA strategy. Such CuO forms a smooth layer coated on the internal walls of SBA-15, which contributes to the spatial order and results in less-blocked mesopores. However, the aggregation of CuO takes place in CuCS material containing 6.7 mmol•g−1 copper, which generates large CuO particles of 21.4 nm outside the mesopores. We reveal that the high dispersion extent of CuO is ascribed to the abundant silanols, as well as the confined space between template and silica walls provided by as-prepared SBA-15. The SPA strategy allows template removal and precursor conversion in one step, avoids the repeated calcination in conventional modification process, and saves time and energy. We also demonstrate that the CuAS material after autoreduction exhibits much better adsorptive desulfurization capacity than CuCS. Moreover, the adsorption capacity of regenerated adsorbent can be recovered completely.
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Catalysis Today
doi:10.1016/j.cattod.2010.08.020 How to Cite or Link Using DOI
Copyright © 2010 Elsevier B.V. All rights reserved.
Formaldehyde activation by Cu(I) and Ag(I) sites in ZSM-5: ETS-NOCV analysis of charge transfer processes
E. Broclawika, J. Załuckab, P. Kozyrab, M. Mitorajb and J. Datkab
broclawi@chemia.uj.edu.pl
a Institute of Catalysis, Polish Academy of Sciences, ul. Niezapominajek 8, 30-239 Krakow, Poland
b Faculty of Chemistry, Jagiellonian University, ul. Ingardena 3, 30-060 Krakow, Poland
Abstract
Adsorption and activation of formaldehyde molecule by copper and silver sites in ZSM-5 was studied by combined QM/MM methodology. ETS-NOCV analysis was applied to decompose the deformation density (the difference between electron densities of composed systems and non-interacting fragments) into independent density flow channels. The analysis disclosed that the bonding of formaldehyde by the metal site may be described in terms of lone pair donation from carbonyl oxygen to the metal and π*-backdonation from metal d orbitals to antibonding orbital of CO. The former one is responsible for the formation of coordinate bond (“dative covalent”) and the latter one for the activation of carbonyl bond. Cu(I) site is more efficient with respect to both processes than Ag(I) one. Zeolitic environment is shown to weaken the bond between formaldehyde and M(I) with respect to free cations for both metals whereas it enhances π*-backdonation in the case of copper and diminishes π*-backdonation in the case of silver. Calculated red-shifts of CO frequencies agree well with the IR-measured ones and correlate with the degree of π*-backdonation which rationalizes as well very good performance of Cu(I) site compared to Ag(I) as the role of zeolitic framework in modifying exchanged cation properties.
Keywords: QM/MM modeling; Cu(I) and Ag(I) sites in MFI; Formaldehyde activation; Electron density transfer channels; ETS-NOCV analysis
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Fuel Processing Technology
doi:10.1016/j.fuproc.2010.08.018
Copyright © 2010 Elsevier B.V. All rights reserved.
COSMO-RS based predictions for the desulphurization of diesel oil using ionic liquids: Effect of cation and anion combination
R. Anantharaja and Tamal Banerjee, a,
tamalb@iitg.ernet.in
a Department of Chemical Engineering, Indian Institute of Technology Guwahati, Guwahati, 781039, Assam, India
Abstract
Ionic Liquids ILs provide an important alternative in removing aromatic sulphur compounds by Liquid–Liquid Extraction (LLE). A total of 28 anions and 6 cations resulting in 168 possible combinations were screened via COSMO-RS (COnductor Like Screening MOdel for Real Solvents). Initially benchmarking was performed to predict the infinite dilution activity coefficients of thiophene in ionic liquids. Comparison with literature values involving 8 ILs with 20 points gave the average root mean square deviation (RMS) to be 11%. Thereafter artificial simulated diesel, aromatic sulphur compound and the cation and anion combination was used to predict the capacity (C) and selectivity (S) at infinite dilution. In general the selectivities were found to decrease in the following order: thiophene (4–24) > benzothiophene (2–12)> dibenzothiophene (1–7). The different hetero atom (N,S,O) and its location in the cation structure strongly influenced the selectivity and capacity at infinite dilution for all the three aromatic sulphur compounds. It was found that the cation without the aromatic ring combined with anions having sterical shielding effect such as [SCN], [CH3SO3], [CH3COO], [Cl], and [Br] proved to be the most favourable IL for desulphurization. [EMMOR][SCN] proved to be the most viable IL for the removal of all the three aromatic sulphur compounds.
Keywords: COSMO-RS; Ionic liquids; Thiophene; Benzothiophene; Dibenzothiophene; Desulphurization
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Invite Jean Steinhardt (LinkedIn Profile: www.linkedin.com/in/jeansteinhardtresearch) to join your LinkedIn Network

Friday, October 15, 2010

The training imperative: LinkedIn Group Petroleum Downstream

“Give fools their gold, and knaves their power; let fortune's bubbles rise and fall; who sows a field, or trains a flower, or plants a tree, is more than all.” -- John Greenleaf Whittier (American Writer, 1807-1892)
“Recent research has proven: Trains do not run on time but on electricity” -- Loesje (Dutch Fictional character "Active and International girl", b.1983)


Here is today’s offering, which I found using the EbscoHost Visual Search feature …

Separation Science and Technology , 44: 971–982 , 2009
Desulfurization of Diesel Fuel by Extraction with Lewis-Acidic Ionic Liquid
Hongs huai Gao, Jianm in Xi ng, Yugu ang Li, Wangli ang Li, Qingfen Liu, and Huizhou Liu
Key Laboratory of Green Process and Engineering, State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, China
Abstract: Ionic liquids were found to be highly selective for the extractive removal of aromatic sulfur compounds from fuels at room temperature. The efficiency of ionic liquids for the removal of aromatic sulfur compounds is dependent on the properties and structure of the ionic liquids. In this work, the Lewis-acidic ionic liquid 1-butyl-3-methylimidazolium tetrahalogenoferrate(III) ([BMIM] [FeCl]) was synthesized and demonstrated to be more effective for the removal of aromatic sulfur compounds from diesel over ionic liquids 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF4]) and 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM] [BF46]) because of its Lewis-acidic property. The ionic liquids favorably extracted organic compounds with a higher density of aromatic p-electrons. [BMIM][FeCl] ionic liquid can be regenerated through reextraction by hexane, and could be used in multiple steps for the removal of sulfur compounds from diesel.


Training is one of the casualties of the current economic climate. As one who specializes in training people to maximize their online search effectiveness, I was interested by a recent comment in a LinkedIn group I belong to.

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Dr Rajan
Many top executives believe that Training of their employees is only a valueless investment until a disaster takes place. Failure to control disasters is the outcome of ignorance and poor knowledge in understading their own system. Recent episodes in the oil & gas industry proves this.Yet top executives don't seem to have learnt any lesson from these disasters
Education
Birla Institute of Technology and Science Ph.D, Chemical Engimneering 1989 – 1993
Written 4 books on Energy Efficiency optimization, published by Tata McGrawHill India, McGrawHill US, Penwellpublishers, US, Productivity and Quality Publishers, India.
Thesis titled ' Computer Applications and Decision Support System for efficient management of process industries ' has won International recognition.
Paper titled 'Cost effectiveness in the refining sector' won the first prize in a competition.
Developed many application software for the industry.
Activities and Societies: Computer Simulation Society, Chamber of Commerce, Inst of Engineers / Plant Engineers and many more.

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In the spirit of the above discussion, here are two tips to help you get the most out of EbscoHost’s Academic Search Complete.

EbscoHost: Two Tips
(1) Visual search
(2) Full text only search box


EbscoHost’s Visual search feature enhances its advanced search feature by providing hyperlinked subtopics that enable you quickly to sharpen the focus of your search. It can be a great time saver compared to the traditional approach.

Another time saver … check the box that limits your results to “full text only.” You will save time by avoiding all those abstracts that require a second effort to acquire the full text from some other source. Of course, in some cases you may need all those abstracts. But if you are simply doing background research, or if you are writing a term paper, “full text only” may be the way to go.

Saturday, October 9, 2010

Tedium … slogging through (why you need a librarian)

“Housework is a treadmill from futility to oblivion with stop-offs at tedium and counter productivity.” -- Erma Bombeck (U.S. humorist, 1927-1996)

Librarians maintain a low profile. During my career it was not unusual for me to introduce myself as the corporate librarian only to be told, “I didn’t even know we had a library in this company.” As to why we seem to blend into the background is a topic for a future post.

For now I want you to (a) find out if your company supports a library and (b) if it does, to get to know your librarian.

And here is an example of how your friendly information professional can help.

During my periodic scans for desulfurization related items, I ran across a device called HydroSeptor™. An initial search on HydroSeptor™ resulted in several sites associated with inventor Jerry Edmondson. Trouble is, there seems to be precious little about either the inventor or his inventions or his companies that is not produced by Mr. Edmondson himself.

Now imagine that your company is approached by a HydroSeptor™ representative. He persuades you that the HydroSeptor™ is just what your company needs. The representative describes the HydroSeptor™ in the following terms …

“This Patented HydroSeptor(tm) configuration applies heat and FCRS (forced coalescing rapid separation) coalescence to help remove water, salt and other impurities from oil. Mechanical Forced Coalescing enhances the dehydration process and the addition of Adjustable Fluid-Dynamic Flow Control will ensure top performance of the HydroSeptor throughout the life of an oil field”
source:
http://www.hydroseptor.com/

Your company is interested, but wants to do due diligence. One part of that due diligence is to search for publicly available information on the inventor, his inventions, and his companies.

Much of the search involves tedious clicking through page after page of Google® and Yahoo!® search results. Googling for “Jerry Edmondson,” for example, results in 28 pages of results. Since there is so little available on “Jerry Edmondson,” it is worth clicking through every page to be sure every little crumb of relevant information is gleaned.

You could do this, but you have (I hope) many other things on your plate. This is where your corporate information professional can help. It is what we get paid to do. We are good at it. And we are glad to do it.

And there’s more. Your librarian probably has access to a number of databases that, due to cost considerations, the company as a whole does not. So he or she can search …

• The D&B database to get a sense of the credit worthiness of Mr. Edmondson’s companies
• The Dialog databases, including Compendex and other technical databases, for a list of articles written by Jerry Edmondson
• The LexisNexis database, for information on lawsuits that Jerry Edmondson may be involved in

Finally, if you are a do-it-yourselfer, your librarian can help you devise search strategies that will maximize your search effectiveness.

And, in case you are interested in Jerry Edmondson’s heavy oil treating devices, here is what I found …

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Google Scholar advanced search: Author: "jerry edmondson"

Geothermal actuated method of producing fresh water and electric powerJM Edmondson, MH Smoot - US Patent 4,091,623, 1978 - Google Patents
Page 1. United States Patent Edmondson et al. [ii] 4,091,623 [45] May 30,1978 [54]
GEOTHERMAL ACTUATED METHOD OF PRODUCING FRESH WATER AND ELECTRIC
POWER [76] Inventors: Jerry M. Edmondson, 1526 Delta, Apt. C, San Gabriel, Calif. ...
Cited by 13 - Related articles - All 4 versions

[CITATION] Polarized auxiliariesJA Edmondson - Linguistic categories: Auxiliaries and related puzzles, 1983
Cited by 11 - Related articles

Oil, water and gas separatorJM Edmondson - US Patent 5,865,992, 1999 - Google Patents
Page 1. United States Patent Edmondson US005865992A [ii] Patent Number: [45] Date of
Patent: 5,865,992 Feb. 2, 1999 [54] OIL, WATER AND GAS SEPARATOR [76] Inventor: Jerry
M. Edmondson, 510 Canal St., Newport Beach, Calif. 92663 [21] Appl. ...
Cited by 11 - Related articles - All 2 versions

Energy conserving method of water treatmentJM Edmondson - US Patent 5,484,534, 1996 - Google Patents
Page 1. United States Patent U9] Edmondson US005484534A [ii] Patent Number: [45] Date of Patent:
5,484,534 Jan. 16,1996 [54] ENERGY CONSERVING METHOD OF WATER TREATMENT [76]
Inventor: Jerry M. Edmondson, 510 Canal St., Newport Beach, Calif. ...
Cited by 8 - Related articles - All 2 versions

Method and apparatus for oil/water de-emulsificationJM Edmondson - US Patent 5,714,048, 1998 - Google Patents
Page 1. United States Patent Edmondson US005714048A [ii] Patent Number: [45] Dale of Patent:;
5,714,048 Feb.. 3, 1998 [54] METHOD AND APPARATUS FOR OIL/ WATER DE-EMULSIFICATION
[76] Inventor: Jerry M. Edmondson, 510 Canal St., Newport Beach, Calif. ...
Cited by 4 - Related articles - All 2 versions

Oil, water and gas separator for swaying serviceJM Edmondson - US Patent App. 10/337,502, 2003 - Google Patents
Page 1. US 20040129633A1 (19) United States (12) Patent Application Publication
(io> Pub. NO.: US 2004/0129633 Al Edmondson (43) Pub. Date: Jul. 8,2004 (54) OIL,
WATER AND GAS SEPARATOR FOR SWAYING SERVICE ...
Cited by 2 - Related articles - All 4 versions

Energy conserving oil and water processing vesselJM Edmondson - US Patent 5,902,483, 1999 - Google Patents
Page 1. United States Patent Edmondson US005902483A [ii] Patent Number: [45] Date of Patent:
5,902,483 May 11,1999 [51] [52] [54] ENERGY CONSERVING OIL AND WATER PROCESSING
VESSEL [76] Inventor: Jerry M. Edmondson, 510 Canal St., Newport Beach, Calif. ...
Cited by 1 - Related articles - All 2 versions

Hydrodynamics control method and apparatusJM Edmondson - US Patent App. 10/792,197, 2004 - Google Patents
Page 1. US 20050194044A1 (19) United States (12) Patent Application Publication
(io> Pub. NO.: US 2005/0194044 Al Edmondson (43) Pub. Date: Sep. 8,2005 (54)
HYDRODYNAMICS CONTROL METHOD AND APPARATUS ...
All 2 versions

Energy efficient pyrolytic processing ovenJM Edmondson - US Patent 7,032,525, 2006 - Google Patents
Page 1. US007032525B1 (12) United States Patent Edmondson (io) Patent No.: US
7,032,525 Bl (45) Date of Patent: Apr. 25, 2006 (54) ENERGY EFFICIENT PYROLYTIC
PROCESSING OVEN (76) Inventor: Jerry M. Edmondson ...
Related articles - All 5 versions

PYROLYTIC RESOURCE RECOVERY SYSTEMJ EDMONDSON - WO Patent WO/2007/024,687, 2007 - wipo.int
AE, AG, AL, AM, AT, AU, AZ, BA, BB, BG, BR, BW, BY, BZ, CA, CH, CN, CO, CR, CU, CZ, DE,
DK, DM, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, HN, HR, HU, ID, IL, IN, IS, JP, KE, KG,
KM, KN, KP, KR, KZ, LA, LC, LK, LR, LS, LT, LU, LV, LY, MA, MD, MG, MK, MN, MW, MX, ...
Cached - All 2 versions

Oil production processing system for swaying serviceJM Edmondson - US Patent App. 10/338,157, 2003 - Google Patents
Page 1. US 20040129426A1 (19) United States (12) Patent Application Publication
(io> Pub. NO.: US 2004/0129426 Al Edmondson (43) Pub. Date: Jul. 8,2004 (54)
OIL PRODUCTION PROCESSING SYSTEM FOR SWAYING ...
Related articles - All 4 versions

Versatile rapid thermal process ovenJM Edmondson - US Patent App. 11/147,764, 2005 - Google Patents
Page 1. US20060278141A1 (19) United States (12) Patent Application Publication
GO) Pub. NO.: US 2006/0278141 Al Edmondson (43) Pub. Date: Dec. 14,2006 (54)
VERSATILE RAPID THERMAL PROCESS OVEN (76) Inventor ...
Related articles - All 4 versions

Energy efficient compact oil and water separatorJM Edmondson - US Patent App. 10/828,424, 2004 - Google Patents
Page 1. US 20050230296A1 (19) United States (12) Patent Application Publication
(io> Pub. NO.: US 2005/0230296 Al Edmondson (43) Pub. Date: Oct. 20,2005 (54)
ENERGY EFFICIENT COMPACT OIL AND WATER SEPARATOR ...
Related articles - All 4 versions

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Let your friends & colleagues know about the Desulfurization Blog: http://www.desulf.blogspot.com/

Monday, October 4, 2010

Combine free tools to maximize your effectiveness: Google & LinkedIn

“Words -- so innocent and powerless as they are, as standing in a dictionary, how potent for good and evil they become in the hands of one who knows how to combine them.” -- Nathaniel Hawthorne (American short-story Writer and Novelist, 1804-1864)

As always, this post is about two things … Desulfurization resources (that’s one) … and how to access those resources (that’s two).

Today I’d like you to consider the power of combining membership in a specific LinkedIn group … let’s say, Heavy Oil … with the ability to add an RSS feed to your Google home page.

Both of these tools are free. Both are useful in their own right. But when combined effectively, the two tools multiply their usefulness by an order of magnitude.

Here, as an example, is what happened to me. As a member of the LinkedIn Heavy Oil group, I received the following notice …
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LinkedIn Groups
Group: Heavy Oil
Subject: Announcement from Heavy Oil
Hello everybody,
Just to let you know that I recently added an RSS news feed from heavyoilinfo (Schlumberger). Heavy oil news will appear in a banner, at our main page. I hope you enjoy this feature.
Regards,
Nestor
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Visiting the HeavyOilInfo site (http://www.heavyoilinfo.com/) I found a number of interesting posts, including …

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Blog
Opinions and thoughts from Dr. Kambiz Safinya (LinkedIn Profile:
http://www.linkedin.com/pub/kambiz-safinya/15/755/2b) .

ESP performance and reliability in heavy oil
SPE paper, "The Quest To Understand ESP Performance and Reliability at 220C Ambient and Beyond", presented at the 2009 SPE Annual Technical Conference and Exhibition in New Orleans discusses how new and improving high-temperature electric submersible pump (ESP) systems allow for more efficient production and reduced costs in heavy oil SAGD production.
Read More…

Evaluation of high rate artificial lift in Oman's heavy oil fields
In the northern region of Oman, PDO operates a heavy oil field produced from naturally fractured carbonates. In order to increase and extend production, various thermal EOR methods combined with advances in artificial lift are being evaluated.
Read More…

Geophysical monitoring of heavy oil
In our recent feature article, we discussed the use of geophysical monitoring in heavy oil with Bob Godfrey, Principal Geophysicist at the Schlumberger Heavy Oil Regional Technology Center in Calgary.
Read More…

Polymer flooding in heavy oil environments
This SPE paper discusses a new approach to improve the performance of polymer flooding in heavy oil environments.
Read More…
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I liked what I saw, so I added the blog as a feed to my iGoogle page. If you have never added a feed to your page before, use the following instructions …

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Firefox users:
- Click on the iGoogle tab where you'd like to create the RSS feed gadget.
- Then visit the site or blog you'd like to subscribe to.
- Click on the orange square RSS feed icon which can usually be found in the toolbar or somewhere within the website, usually at the top.
- Choose Google from the drop down menu and if you have not specified before, select Add to Google Homepage.
- It will automatically appear in your iGoogle account under tab you last visited.

Internet Explorer and other browsers:
- Copy the RSS feed URL (In this case, the URL is: http://www.heavyoilinfo.com/blog-posts/blog/RSS)
- At iGoogle, click on the "Add Stuff" in the upper right-hand corner.
- On the left, click on "Add feed or gadget" and paste the URL in the field.
- The RSS gadget will automatically appear in your iGoogle account under tab you last visited.
source:
http://www.butterscotch.com/tutorial/Subscribing-To-RSS-Feeds-With-IGoogle
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Speaking of feeds, consider adding the Desulfurization Blog (http://www.desulf.blogspot.com/) as a feed on your home page.