Tuesday, June 12, 2018

Die, dibenzothiophene, die


Dibenzothiophene is one of the things I follow because it is such a difficult problem in desulfurization of hydrocarbons.

However, I also follow lots of other technical issues. To limit my browsing time and increase my sleep time, I try to limit the amount of stuff that lands in my inbox.

TIP: If you, like me, follow more than one technical issue, consider fine tuning your email alerts.  For example, while desulfurization may be a major interest, you may be able to save yourself time by focusing on a particularly recalcitrant aspect of desulfurization … dibenzothiophene.

I have set up a Google® Scholar (https://scholar.google.com/) alert that suits my purposes:

allintitle: dibenzothiophene

This limits the number of items I have to consider each morning. Of course, it is not ideal for in depth research, but it provides me enough information to determine whether I have to go deeper.

Your requirements will differ … but the principle remains the same. There are only 24 hours in the day. So use them wisely. Now, go back to sleep.

P.S. Here are some recent results from allintitle: dibenzothiophene

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Catalytic oxidative desulfurization of dibenzothiophene utilizing molybdenum and vanadium oxides supported on MCM-41
A Teimouri, M Mahmoudsalehi, H Salavati - International Journal of Hydrogen Energy, 2018
As a series of bimetallic nanocatalysts, molybdenum/vanadium oxides supported on
the silica (MoO 3/V 2 O 5/MCM-41) were prepared by the impregnation. Their
catalytic activity in the oxidation of dibenzothiophene was investigated using H 2 O 2 …


New Insights on the role of sulfur vacancies on dibenzothiophene hydrodesulfurization over MoS 2 edges
S Sharifvaghefi, B Yang, Y Zheng - Applied Catalysis A: General, 2018
Experimental and computational studies were performed to investigate the effect of
varying sulfur coverage over MoS 2 in hydrodesulfurization (HDS) of
dibenzothiophene (DBT). Hematite and iron particles were employed as H 2 S …




[HTML] Oxidative desulfurization of dibenzothiophene catalyzed by α-MnO 2 nanosheets on palygorskite using hydrogen peroxide as oxidant
X Yu, P Han, Y Li - RSC Advances, 2018
Palygorskite (Pal)-supported α-MnO2 nanosheets (Ns-MnPal) combine the
adsorption features of Pal with the catalytic properties of α-MnO2 nanosheets. They
were prepared and examined in the catalytic oxidative desulfurization (ODS) of …




Synthesis of Ag-AgBr/Al-MCM-41 nanocomposite and its application in photocatalytic oxidative desulfurization of dibenzothiophene
XN Pham, BM Nguyen, HT Thi, H Van Doan - Advanced Powder Technology, 2018
A series of Ag-AgBr/Al-MCM-41 nanocomposites were synthesized by dispersion of
Ag-AgBr on mesoporous silica Al-MCM-41 obtained from natural bentonite. The
synthesized Ag-AgBr/Al-MCM-41 composites with Ag nanoparticles growing on the …




Effects of gallium addition to mesoporous alumina by impregnation on dibenzothiophene hydrodesulfurization performances of the corresponding NiMo supported …
W Zhou, Y Zhang, X Tao, Y Zhou, Q Wei, S Ding - Fuel, 2018
The effects of gallium (Ga) modification on mesoporous Al 2 O 3 (MA) were studied,
focusing on the morphology changes of the active phases and the application as
catalyst support for catalytic performances for dibenzothiophene (DBT) …



Synthesis of Silica@ C-dots/Phosphotungstates Core-Shell Microsphere for Effective Oxidative-Adsorptive Desulfurization of Dibenzothiophene with Less Oxidant
Y Zhang, R Wang - Applied Catalysis B: Environmental, 2018
A core-shell microsphere catalyst with a solid silica core and a mesoporous shell
made up of quaternary ammonium phosphotungstate and carbon dots (C-dots) was
successfully synthesized for the oxidative-adsorptive desulfurization (OADS) of …





Oxidative desulfurization of dibenzothiophene and diesel by hydrogen peroxide: Catalysis of H 3 PMo 12 O 40 immobilized on the ionic liquid modified SiO 2
X Li, J Zhang, F Zhou, Y Wang, X Yuan, H Wang - Molecular Catalysis, 2018
Here we reported an oxidative desulfurization system for oxidation of sulfur-
containing compounds in model oil and diesel by catalysis using SiO 2-supported
phosphomolybdate hybrid material with 30% H 2 O 2 aqueous solution as the …




Removal of Benzothiophene and Dibenzothiophene from Hydrocarbon Fuels using CuCe Mesoporous Y Zeolites in the Presence of Aromatics
KX Lee, G Tsilomelekis, JA Valla - Applied Catalysis B: Environmental, 2018
Adsorptive desulfurization of sulfur compounds in transportation fuels, such as
benzothiophenes from gasoline and jet fuels and dibenzothiophenes from diesel,
can be inhibited by diffusion limitations in porous materials as well as the presence …





[PDF] Oxidation of Dibenzothiophene in Model Diesel Using Hydroperoxide Generated via In-Situ Reaction of Octane with Oxygen
G Erliang, L Jianxin, H Xiaoqiao, D Yongshen… - 2018
The potential of carrying out oxidative desulfurization (ODS) using oxygen as an
oxidant was explored in this work. n-Octane firstly reacted with oxygen to produce
hydroperoxides in-situ, which were then used as oxidants to oxidize the …




[PDF] Desulfurization of the dibenzothiophene (DBT) by using imidazolium-based ionic liquids (Ils)
B Kazmi, A Zahoor, H Saud - Materials Physics and Chemistry, 2018
Abstract In this work we have examined the industrial scale extraction process of
ultra low sulfur diesel with the help of simulation software ASPEN Plus®. This work
focuses on the [Cnmim][BF4](imidazolium-based) ionic liquid and employed it in the …




Synthesis of an Ni 2 P catalyst supported on Na-MCM-41 with highly activity for dibenzothiophene HDS under mild conditions
H Song, F Zhang, N Jiang, M Chen, F Li, Z Yan - Research on Chemical Intermediates
Abstract A novel and simple method to synthesize supported Ni 2 P/Na (x)-MCM-41
catalysts (where x is the mass fraction of Na-to-MCM-41 in terms of percentage) at a
lower reduction temperature by incorporation of Na was described. The catalysts …


NiMo catalysts supported on Al, Nb, Ti or Zr-containing MCM-41 for dibenzothiophene hydrodesulfurization
FJ Méndez, G Bravo-Ascención, M González-Mota… - Catalysis Today, 2018
Abstract xMCM-41 materials (x= Al, Nb, Ti or Zr) with nominal x loading of 0.5 mmol/g
were prepared by chemical grafting of Al 2 O 3, Nb 2 O 5, TiO 2 and ZrO 2 precursors
and used as supports for NiMo/xMCM-41 catalysts. Small-angle XRD …



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