Friday, July 29, 2016

Target

“To be sure of hitting the target, shoot first, and call whatever you hit the target -- Ashleigh Brilliant (English Author and Cartoonist, b.1933)

Searching the USPTO Patent Applications Database (http://appft.uspto.gov/netahtml/PTO/search-bool.html) for DESULFURIZATION, I found …

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Targeted Desulfurization Apparatus Integrating Oxidative Desulfurization And Hydrodesulfurization To Produce Diesel Fuel Having An Ultra-Low Level Of Organosulfur Compounds
United States Patent Application 20160208179
Bourane; Abdennour ;   et al.   July 21, 2016
Abstract
Deep desulfurization of hydrocarbon feeds containing undesired organosulfur compounds to produce a hydrocarbon product having low levels of sulfur, i.e., 15 ppmw or less of sulfur, is achieved by flashing the feed at a target cut point temperature to obtain two fractions. A first fraction contains refractory organosulfur compounds, which boil at or above the target cut point temperature. A second fraction boiling below the target cut point temperature is substantially free of refractory sulfur-containing compounds. The second fraction is contacted with a hydrodesulfurization catalyst in a hydrodesulfurization reaction zone operating under mild conditions to reduce the quantity of organosulfur compounds to an ultra-low level. The first fraction is contacted with an oxidizing agent and an active metal catalyst in an oxidation reaction zone to convert the refractory organosulfur compounds to oxidized organosulfur compounds. The oxidized organosulfur compounds are removed, producing a stream containing an ultra-low level of organosulfur compounds. The two streams can be combined to obtain a full range hydrocarbon product having an ultra-low level of organosulfur compounds.
Free Full Text Source:  http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO2&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=2&f=G&l=50&co1=AND&d=PG01&s1=desulfurization.TTL.&OS=TTL/desulfurization&RS=TTL/desulfurization
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TIP: Search INVENTOR names in Google Scholar (http://scholar.google.com)  to build a background for the invention.  For example …

Google® Scholar: author:abdennour author:bourane
90 Results ... Here are a few of them ...

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Heats of adsorption of linear and multibound adsorbed CO species on a Pt/Al 2 O 3 catalyst using in situ infrared spectroscopy under adsorption equilibrium
A Bourane, O Dulaurent, D Bianchi - Journal of Catalysis, 2000 - Elsevier
The adsorption of CO (1 and 10% CO/He mixtures, 1 atm total pressure) on a reduced 2.9%
Pt/Al2O3 catalyst in the temperature range 298–740 K is studied using Fourier transform
infrared spectroscopy (FTIR). Several adsorbed CO species on Pt sites are detected at ...
Cited by 81 Related articles All 4 versions Cite Save

Oxidation of CO on a Pt/Al 2 O 3 catalyst: From the surface elementary steps to light-off tests: I. Kinetic study of the oxidation of the linear CO species
A Bourane, D Bianchi - journal of Catalysis, 2001 - Elsevier

The adsorption of CO (1% CO/He mixture) at 300 K on a 2.9% Pt/Al2O3 catalyst leads to the
detection of a strong IR band at 2075 cm− 1 associated with a weak and broad IR band at≈
1850 cm− 1 ascribed to linear (denoted by L) and multibound (Bridged and 3-fold ...
Cited by 80 Related articles All 3 versions Cite Save

Oxidation of CO on a Pt/Al 2 O 3 catalyst: from the surface elementary steps to light-off tests: V. Experimental and kinetic model for light-off tests in excess of O2
A Bourane, D Bianchi - Journal of Catalysis, 2004 - Elsevier
This article is the final part of a study on the CO/O2 reaction over a 2.9% Pt/Al2O3 in line with
the microkinetic approach of the heterogeneous gas–solid catalysis. Mainly, the kinetic
parameters of each elementary step of two kinetic models (Models M1 and M2) ...
Cited by 70 Related articles All 4 versions Cite Save

Heats of adsorption of the linear CO species adsorbed on a Ir/Al2O3 catalyst using in situ FTIR spectroscopy under adsorption equilibrium
A Bourane, M Nawdali, D Bianchi - The Journal of Physical …, 2002 - ACS Publications
The adsorption of CO on a reduced 1% Ir/Al2O3 catalyst has been studied by using Fourier
transform infrared spectroscopy (FTIR) at two constant CO partial pressures P a (200 and
2000 Pa) in the adsorption temperature (denoted by T a) range of 300-740 K. At 300 K, it ...
Cited by 50 Related articles All 4 versions Cite Save

Oxidation of CO on a Pt/Al 2 O 3 Catalyst: From the Surface Elementary Steps to Lighting-Off Tests: II. Kinetic Study of the Oxidation of Adsorbed CO Species Using …
A Bourane, D Bianchi - Journal of Catalysis, 2002 - Elsevier
Experiments in the transient regime using a mass spectrometer as a detector are performed
at T= 300 K on a 2.9% Pt/Al2O3 catalyst to study the oxidation of the linearly adsorbed CO
species (denoted L) with several x% O2/z% Ar/He mixtures (x and z in the range 0.5–4). ...
Cited by 48 Related articles All 4 versions Cite Save

Heats of adsorption of the linear CO species on Pt/Al 2 O 3 using infrared spectroscopy: impact of the Pt dispersion
A Bourane, D Bianchi - Journal of Catalysis, 2003 - Elsevier
In previous studies, it has been shown that the heats of adsorption at several coverages of
each adsorbed CO species (linear, bridged, and threefold coordinated) on a 2.9% Pt/Al2O3
catalyst can be obtained from the change in the IR band area of each adsorbed CO ...
Cited by 47 Related articles All 4 versions Cite Save

Heats of adsorption of the linear CO species adsorbed on a Pt/Al2O3 catalyst in the presence of coadsorbed species using FTIR spectroscopy
A Bourane, O Dulaurent, D Bianchi - Langmuir, 2001 - ACS Publications
The adsorption of CO (1% CO/He mixture, 1 atm total pressure) in the presence of several
gases is studied on a reduced 2.9% Pt/Al2O3 catalyst in the 300-740 K temperature range
by using Fourier transform infrared spectroscopy. A strong IR band is observed at 2075 cm ...
Cited by 41 Related articles All 3 versions Cite Save

Comparison of the Coverage of the Linear CO Species on Pt/Al 2 O 3 Measured under Adsorption Equilibrium Conditions by Using FTIR and Mass Spectroscopy
A Bourane, O Dulaurent, D Bianchi - Journal of Catalysis, 2000 - Elsevier
There is controversy in the literature about the relationship between the IR band area
(denoted by A) of the adsorbed CO species (ie, linear (denoted by L) and bridged (denoted
by B) CO species) on noble-metal-containing solids (supported metal catalysts and single ...
Cited by 40 Related articles All 5 versions Cite Save

Heats of adsorption of the linear CO species on a Pt/Al 2 O 3 catalyst using FTIR spectroscopy: Comparison between TPD and adsorption equilibrium procedures
A Bourane, O Dulaurent, K Chandes… - Applied Catalysis A: …, 2001 - Elsevier
The present study compares the evolution of the IR band of the linear CO species (denoted
by L) adsorbed on a 2.9% Pt/Al2O3 catalyst with the increase in the temperature either in a
helium flow (temperature programmed desorption-infrared experiments denoted by TPDIR ...
Cited by 40 Related articles All 5 versions Cite Save

Oxidation of CO on a Pt/Al 2 O 3 Catalyst: From the Surface Elementary Steps to Lighting-Off Tests: III. Experimental and Kinetic Model for Lights-Off Tests in Excess …
A Bourane, D Bianchi - Journal of Catalysis, 2002 - Elsevier
The adsorption of CO (1% CO/He mixture) at 300 K on a 2.9% Pt/Al2O3 catalyst leads to the
detection of a strong IR band at 2075 cm− 1 associated with weak and broad IR bands in the
range 1900–1700 cm− 1 ascribed to linear (denoted L) and multibound (bridged and ...
Cited by 40 Related articles All 3 versions Cite Save



Thursday, July 21, 2016

Direct Processing of Crude Oil

“The key to your universe is that you can choose.”  Frederick (Carl) Frieseke (American born French Painter, 1874-1939)

According to Bloomberg News, Saudi Arabian Oil Co. and Saudi Basic Industries Corp. are one step closer to building their first plant to process crude directly into chemicals, cutting out a costly intermediate link in the production of plastics.

In the conventional approach, oil companies refine crude oil into transportation fuels.  The byproducts are then used by the petrochemical industry to produce chemicals.

Processing crude directly into chemicals is a more efficient route to plastics production, significantly reducing costs.

Read the complete article by clicking the link below.

Source:  Aramco, Sabic One Step Closer to Turning Oil into Chemicals, Bloomberg News, June 28, 2016 (http://www.bloomberg.com/news/articles/2016-06-28/saudi-aramco-sabic-one-step-closer-to-turn-oil-into-chemicals)
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TIP: Add value to the Bloomberg article by searching Saudi Aramco patents ...

In the USPTO Patent Database (http://appft.uspto.gov/netahtml/PTO/search-bool.html) search Saudi in the Assignee Name field and integrated in All Fields. Advanced users can enter the following search string directly …

AN/saudi AND integrated
NOTE
: Aramco is not a good key word for the Assignee Name field to identify Saudi Aramco patents. Use Saudi instead

One result …

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Integrated hydrotreating, solvent deasphalting and steam pyrolysis process for direct processing of a crude oil
United States Patent  9,382,486
Bourane ,   et al.   July 5, 2016
Assignee: Saudi Arabian Oil Company
Abstract
A process is provided that is directed to a steam pyrolysis zone integrated with a hydrotreating zone and a solvent deasphalting zone to permit direct processing of crude oil feedstocks to produce petrochemicals including olefins and aromatics. The integrated hydrotreating, solvent deasphalting and steam pyrolysis process comprises charging the crude oil to a hydroprocessing zone to produce a hydroprocessed effluent; charging the hydroprocessed effluent to a solvent deasphalting zone to produce a deasphalted and demetalized oil stream and a bottom asphalt phase; thermally cracking the deasphalted and demetalized oil stream in the presence of steam to produce a mixed product stream; separating the mixed product stream; purifying hydrogen recovered from the mixed product stream and recycling it to the hydroprocessing zone; recovering olefins and aromatics from the separated mixed product stream; and recovering pyrolysis fuel oil from the separated mixed product stream.
source: http://patft.uspto.gov/netacgi/nph-Parser?Sect1=PTO2&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&co1=AND&d=PTXT&s1=saudi.ASNM.&s2=integrated&OS=AN/saudi+AND+integrated&RS=AN/saudi+AND+integrated
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Wednesday, July 13, 2016

Aramco Ventures




“Whoever starts out toward the unknown must consent to venture alone” -- Andre Gide (French writer, humanist and moralist, 1947 nobel prize for literature, 1869-1951)

Saudi Aramco, by some accounts the world’s largest oil company, also invests in startup technology firms.  Aramco Ventures (https://aramcoventures.com/) lists the companies it has invested in.  Most are in the upstream part of the oil industry, but its portfolio includes a number of downstream ventures as well.  For example …

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Downstream

ConXtech
A privately-held construction technology company offers ConX®, a Chassis Based Modular™ structural steel system based on standardized moment connections and building assemblies.
Invested in: April 2015
Location: USA
www.conxtech.com
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Siluria
Breakthrough catalyst and process technologies for converting natural gas to liquids or petrochemicals.
Invested in: July 2014
Location: USA
www.siluria.com
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Novomer
A sustainable chemistry company pioneering a family of high performance environmentally responsible polymers and chemical intermediates.
Invested in: November 2013
Location: USA
www.novomer.com
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Rive Technology
Developer of innovative materials-based solutions for catalytic and separations processes in the petroleum refining, chemicals, water and biofuels industries.
Invested in: July 2013
Location: USA
www.rivetechnology.com
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TIP: Visit the Aramco Ventures site (https://aramcoventures.com/) to view the investment strategy, as well as profiles of the other companies they have chosen to invest in.


Wednesday, July 6, 2016

Diesel Technology Forum

“I believe in getting into hot water - it helps keep you clean.” -- G. K. Chesterton (English born Gabonese Critic, Essayist, Novelist and Poet, 1874-1936)

The latest edition of Hydrocarbon Engineering has just been issued. It features an article written by Allen Shaeffer, chief executive of the Diesel Technology Forum (http://www.dieselforum.org/ )

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Clean diesel: the new generation
Allen Schaeffer, Diesel Technology Forum (http://www.dieselforum.org/ ), USA, explains how today's ultra low sulfur diesel fuel, advanced engines and effective emissions control have combined to create a smoke free, clean diesel technology that achieves near zero emissions.
Source: Hydrocarbon Engineering
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TIP: Google® Allen Schaeffer.  One result is the following …

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The TH Interview: Allen Schaeffer, Diesel Technology Forum Executive Director
Andrew Posner
TreeHugger Exclusives (January 16, 2008)
source: http://www.treehugger.com/about-treehugger/the-th-interview-allen-schaeffer-diesel-technology-forum-executive-director.html
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